19. Boccara, A. C., D. Fournier, 'vV. jackson  27. Coufal, H. and P. Hefferle. "Thermal
                                                    Diffusivity Measurements of Thin
     and N.M. Amer. "Sensitive                      Films with a Pyroelectric
     Photothermal Deflection Technique             Calorimeter." Applied Physics A.
                                                    Vol. 38. Berlin, Germany: Springer
     for Measuring Absorption in Optically          Verlag (1985): p 213-219.
    Thin Media." Optics Letters. Vol. S,
     No.9. Washington, DC: Optical             28. Mandelis, A. "Theory of
     Society of America (1980): p 377-379.          Photothermal-\'\'ave Diffraction and
20. Bertolotti, M., G.L. Liakhou,                   Interference in Condensed Media."
                                                   Journal of the Optical Society ofAmerica,
     R. Li Voti, S. Paoloni and C. Sibilia.         series A. Vol. 6, No. 2. \oVashington,
                                                    DC: Optical Society of America
     "Analysis of the Photothermal
     Deflection Technique in the Surface            (1989): p 298-308.
     Reflection Scheme: Theory and
     Experiment." journal ofApplied
    Physics. Vol. 83, No. 2. College Park,
     MD: American Institute of Physics
     (1998): p 966-982.
21. Bertolotti, M., G.L. Liakhou,
     R. Li Voti, S. Paoloni, C. Sibilia and
     N. Sparvieri. A11 Cryostatic Set-Up for
     the Low Temperature Measurements
     ofThermal Diffusivlty with the
     Photothermal Method.'' Review of
    Scientific Instruments. Vol. 66, No. 12.
     College Park, MD: American Institute
     of Physics (1995): p 5598-5602.
22. Bertolotti, M., G.L. Liakhou, R. Li
     Voti, Ruo Peng Wang, C. Sibilia,
     A.V. Syrbu and V.P. Yakovlev: 11An
     Experimental and Theoretical
     Analysis of the Temperature Profile in
     Semiconductor Laser Diodes Using
     the Photodeflection Method."
    Measurement Science and Tecllnolagy.
     Vol. 6. London, United Kingdom:
     Institute of Physics (1995):
     p 1278-1290.
23. Touloukian, Y.S., R.W. Powell, C.Y. Ho
    and M.C. Nicolaou. Thermophysical
    Properties ofMatter. Vol. 10. New York,
     NY: Plenum (1973).
24. Reyes, C.B., ]. jaarinen, L.D. Favro,
    P.K. Kuo and R.L. Thomas. Review of
    Progress in Quantitative Nondestructire
     Evaluatiou~ ed. D.O. Thompson and
     D.E. Chimenti. Vol. 6. Ne\\' York, NY:
     Plenum (1987): p 271.
25. Bertolotti, M., R. LiVoti, G. Liakhou
     and C. Sibilia. "On the
     Photodeflection Method Applied to
     Low Thermal Diffusivity
    Measurements." Rel'iew ofScientific
    Instruments. Vol. 64, No. 6. College
     Park, MD: American Institute of
     Physics (1993): p 1576.
26. Bertolotti, M., V. Dorogan, G.
    Liakhou, R. LiVoti, S. Paoloni and
     C. Sibilia. "New Photothermal
     Deflection Method for Thermal
     Diffusivity Measurement of
    Semiconductor \Vafers." Rel'iew of
    Scientific Instruments. Vol. 68, No. 3.
     College Park, MD: American Institute
     of Physics (1997): p 1521-1526.
86 Infrared and Thermal Testing
CHAPTER
     Fundamentals of
Infrared Radiometry
          Stephan Offermann, Universite de Reims
          Champagne-Ardennes, Reims, France
          jean Louis Beaudoin, Universite de Reims
          Champagne-Ardennes, Reims, France
          Christian Bissieux1 Universite de Reims
          Champagne-Ardennes, Reims, France
PART 1. Fundamental laws
Electromagnetic Spectrum                        unchanged in the medium, whereas the
and Thermal Radiation                           wavelength /, becomes:
The intimate nature of radiation ·was first     (4)
established by Maxwell as electromagnetic
waves, ranging from cosmic rays to radio        and the wave velocity F becomes:
waves and including gamma rays, X-rays,
ultraviolet radiation, visible light, infrared  (5) {/ = !___
radiation and microwaves. The behavior
of the electromagnetic waves is ·well                                       II
described by a set· of mathematical
relations, named ~vfaxwell's eguations. 1•2        The frequent use by spectroscopists of
In a vacuum, the most simple solution is        the Wtll'£' llllmber a instead of the
the monochromatic plane waw:                    wavelength should also be mentioned.
                                                The wave number, a= /,- 1, is commonly
(1) E                                           expressed in cm-1.
                                                   The expression of a plane
                                                monochromatic wave, propagating along
                                                the Z axis in the medium, becomes:
                                                (6) E     E0 exp(-2nk_!/,_o_)
·where £0 is amplitude, v is frequency, z is           x  exp [J.2 rr ( vt  -  ··1),1z )]
distance from the origin of the coordinate                                        0
axis and /..0 is wawleugt/1 in a vacuum. At
any instant, the wave amplitude is                 The first exponential term represents
spatially periodic and the wavelength           the progressive attenuation of the
represents the spatial period. The              amplitude, as long as the wave travels
wavelengths corresponding to the                deeper in the medium, according to the
radiation visible to the human eye range        value of the extinction index kl,!)\' The
from about 0.4 to 0.8 pm ·whereas the           ab5orpliou cocfficimt K for energy is
infrared domain extends beyond 100 pm.          proportional to the square of amplitude
The wavelength appears related to the           and is related to k:
velocity c of the electromagnetic wave in
a vacuum:                                       (7) K
                   c                               Various processes can be responsible for
                    v                           the emission of radiation: collision with
    \'\'hen the ·wave has to propagate in <l    particles in electric discharges, excitation
medium, things are much more involved.          by light beams or heating of matter.
On a microscopic scale, it is clear that the
electric and magnetic fields of the wave        Among these processes, only the latter
do interact with the electric charges of        relates to thermal radiation.
matter. Because the present discussion is
concerned only with the macroscopic                A medium is said to emit thermal
scope of things, Maxwell's theory can still     radiation when the interactions between
be used provided that a new macroscopic
parameter is introduced, the complex            its constitutive particles are strong enough
refractive index of the medium:                 to keep their enert,'T distribution in a
                                                statistical t'quilibrium. This equilibrium i~
(3) ll ~ II - ik                                mathematically described by a function of
where n is the refractive index and k is the    the local temperature- generally the
extinction index. The frequency v remains       !vlaxwcll-Boltzmann's distribution. Then
                                                the medium is at local tlu:rmutlynmuic
                                                equilihrium. For example, in an electric
                                                wire heated by the joule effect, the
                                                unceasing collisions between electron.<.
88 Infrared and Thermal Testing
and atoms permit establishment of this             This quantity wil1 appear to be
statistical equilibrium. This is not the Ci}se  fundamental, because any imaging
                                                system, such human eyes or the detector
in the rarefied atmosphere of a discharge       of infrared cameras, responds
lamp, where the electric arc is able to         proportionaBy to L. Because no varieties
force a particular energy distribution          of radiance are usually introduced, it must
                                                be specified whether a radiance is emitted
mainly related to its strength.                 or received or reflected or even
                                                transmitted at a surface. In the absence of
   At local thermodynamic equilibrium,          a specification, it is assumed that the
the mathematical expression for the             radiance of a surface is derived from the
                                                radiosity.
spectral distribution of emitted radiation
is the product of a universal expression,          Of less utility is the quantity radiant
depending only on temperature (Planck~~         i11tensity I, mainly useful to characterize
                                                point sources:
law)1 by a quantity specific to the
material: its emissivity. In this case, where   (10) I ~ eM>
radiation has a thermal nature1 and in the
usual conditions of temperature, the                                 dQ
emission 'i\'avelengths ·will appear mainly
in the infrared range.                          However, the word iutensit)' to describ<:'
                                                radiance must he used carefully in many
Radiometric Quantities                          contexts.
Some adequate quantities must now be            Blackbody Radiation
defined to quantify the radiation leaving
or reaching a surface. At first, two            The basic laws of thermal radiation
categories of terms are to be considered:       describe the emission of an ideal emitting
                                                material, usually known as a blackhod)'.:P
  1. Total quantities deal with energy          This emission, for which physical laws are
    summed over the whole spectrum;             thoroughly settled, actually exists inside
                                                an isothermal closed cavil}~ whatever the
 2. Spectral or monochromatic quantities        nature of its walls. The emission of this
    characterize the ener&'J' contained in a    completely closed isothermal cavity is
    narrm\' interval of "\vavelength; these     impossible to observe. Indeed, a small
    will be written with a subscript],.         aperture must be made through a cavity
                                                wall. The resulting device is called a
In the same way as for conduction and           laboratory blackbody. Geometrical
convection, the radiant flux or radiant         calculations show that its actual emission
power <P, measured in watt, is the time rate    is very close to that of the ideal
of radiant energy. The radiant flux per         blackbody, which represents both the
unit area, over all directions of space, is     perfect absorber and the best emitter at
thus measured in watt per square meter          local thermal equilibrium.
(W·nr2):
                                                   The total emissive power /o.J0 (\·V·m-2) of
(8) tp  d<t>                                    an ideal blackbody, summed over the
        dS                                      whole spectral range, is given by the
                                                Stefan-lloltzmal'ln law:
   If the energy is emitted by the surface,
then this quantity is called emissil'e          (11) d<t>
                                                           dS
power M.
                                                with:
   If the energy is received by the surface,
                                                (12) (J
then it is called irmdiance E.
                                                   Because the total radiance of thl' ideal
   If the energy is leaving the surface,        blackbody 1.0 (\·V·m-2·sr-1) is isotropic, the
whatever the physical cause of which
                                                blackbody is said to be lambertian and its
(emitted plus reflected plus eventually         radiance is simply related to its emissive
transmitted), then it is called radiosit}' f.
                                                power:
   So, 111, E and I appear as varieties of the
same physical species <fl1 introduced to
describe more precisely the radiation
exchanges at a surface element.
   To quantify now the tlux passing
through a small surface of area dS within
a small solid angle dO., around a direction
making an angle 0 with the normal to the
surface, the radiance L (or lwuiuance), is
defined and measured in watt per square
meter per steradian (\·V·nr2·sr 1):
(9) L       d2cJ>
        dSdQcose
                                                (13) L"  n
           dtp
        d!lcosO
                                                         Fundamentals of Infrared Radiometry 89
Planck's Jaw, already evoked, describes   shorter wavelengths. Indeed, in an
the spectral distribution of the flux        obscured room, the blackbody emission
                                             becomes visible (dark red) for a
emitted by the blackbody in a vacuum         tempemture higher than 823 K (550 "C =
(very close to that emitted in air, where),  1020 °F).
is close to ),0 ):
                                                It must be pointed out that more than
(14)        dM 0                             95 percent of blackbody radiation lies in a
             d),                             spectral range between 0.5 J. m and 5 )'111 -
                                             that is, one order of magnitude in
            1)),5 (exp_llc_ -                l\'avelength. For a blackbody at room
                      ki.T                   temperature, Am is about 10 pm
               nC11.-5                       (2898/293) and the essential of the
            expC--z- -                       emitted energy lies in the infrared
                  ),T                        between Sand 50 run. At 823 K (550 oc =
with the first and second radiation          1020 oF), ),m is about 3.5 pm (2898/823)
constants defined respectively as    C1 =    and the main emission still lies in the
2!JcZ ~ 1.191 I0-16 W·ll1 2 = 3,742  !QH     infrared, but the human eye is a very
                                             good detector and sees the tiny emission
W·nr2·p111'4 and C2 = IIck-1 = 1.4388 104    at the limit between red and infrared.
run-K.                                          The sun radiates nearly like a
   M01, is the spectral {or monochromatic)   blackbody at 5800 K
emissive power of the blackbody. The
                                             (5500 oc = 10000 °F). The solar surface
associated spectral radiance L). is
                                             exhibits its emission peak around 0.5 pm
isotropic:                                   and essentially emits between 0.25 t-Jlll
                                             and 2.5 pm. Aside from this shift toward
(15) L~                                      shorter ·wavelengths, it should not be
                                             forgotten that a hotter blackbody always
                                             emits more than a colder one, at any
                                             wavelength.
(16) L~     dL0
            die
            dSdQ cosSri),
(17) 21!c2
                    ics ( e x pli-e-
                               kAT
At a given blackbody temperature, M 0,
A1f, L0 and Lf are thus weB known and
easily computable.
   Mf presents a maximum value at a
\<Vavelength Am, simply related to the
absolute temperature by \•Vien's law:
(18) ),,T = 2898 run-K = C1
The spectral emissive power M-2m at /,m
follmvs the Jaw:
(19) Mf,
with c4 = 1.287 X w-s (\·V·nr3.K-s).
    Objects at low temperatures are not
actually perceptible to the eye, because
their thermal emission lies mainly in the
infrared. When the temperature of the
blackbody increases, its thermal emission
will contain more and more energy at
90 Infrared and Thermal Testing
PART 2. Radiative Properties of Materials
Directional and Spectral                     which describes the real material's
Emissivities                                 emissive ability versus wavelength and
                                             emissive direction. (See Fig. 1.) Note that
Because the blackbody is an ideal radiator,  the knowledge of E't. or €1.. can be restricted
it emits as much radiant energy as           to the 0.5 ]..111 to S A111 interval because L0>.
possible at local thermodynamic              is negligible out of this interval. From the
equilibrium. The emissive power of a real    knowledge of e'1_, the other three
material will then be defined by             emissivities can he derived:
comparison with that of a blackbody at
the same temperature, the _ratio being       (25) € ~
called the emissivity of the material.
                                                      JEt.;4 L}_ d),
   To characterize the angular and spectral
dependence of the emissive behavior of               (J u
the real material, four parameters are
usually defined:3-7
(20) € ~
for total (hemispherical) emissivity;        (26) E    1
                                                     - -JLcosBdn
(21) <' ~ .!-_                                       nL0
                    Lo                                      n
for directional (total) emissivity;
                                                     - 1-JE'L0 cosedn
(22) ''·                                             rrL0
                                                            n
                                                     J~ E'cos8dQ
                                                         n
for spectral (hemispherical) emissivity;     (27) E'
and
                                             (28) €), ~ .r!r .Jr',•cos9dn
(23) <\
                                                                       n
for spectral directional emissivity. The
adjectives between brackets arc usually      A frequently used simplification supposes
not mentioned. The radiances under           the surface to he gm}', meaning that its
consideration here are strictly the emitted  spectral radiative properties do not
ones.                                        depend on wavelength:
   According to these definitions, the four  '·(29) €'·
ratios are obviously equal to unity for a
reference blackbody and range between        and
zero and unity for real materials. The
emissivities are linked by the spatial       (30) E), ~ E
integral relation between emissive power
and radiance:                                   The second usual simplification
                                             supposes the surface to be diffltse,
(24) M  JM,,dk  JLcos8tfQ                    meaning that its directional radiative
        0       n
   The spectral directional emissivity E'J.
appears as the fundamental parameter,
                                                     Fundamentals of Infrared Radiometry 91
properties do not depend on the emission                For the most -common materials,
angle:                                               emissivity tables can be found in the
                                                     literature. Generally, these tables present
and                                                  total emissivities, rarely spectral
                                                     emissivities and almost never directional
(32) e' ~ e                                          emissivities. The tables often give a good
                                                     idea of the approximate emissivity values
   Moreover, the emissivity effectively              but in actual temperature measurement
involved in a radiometric measurement is             conditions the onl>' knowledge of the
actually an averaged value over the                  total emissivity may not be sufficient.
spectral sensitivity range of the
radiometer. Its spectral response 5(/..) is          Absorptivities,
different from zero only over a spectral             Reflectivities and
sensitive interval t'1A of the detection             Transmittivities
device. Then, the effective emissil•ity of the
material over the spectral range of the              Once the emissive behavior of the
apparatus is defined as:                             material has been characterized, the
                                                     response of the material must be·
           Je'1.L~S(i.)di.                           considered when an external radiation
                                                     impinges on its surface. The total
                                      /,),           absorptivity a of a surface element of area
                                                     dS is simply defmed as the ratio between
and would be computed, provided that                 the absorbed flux d<I>a and the incident
e')_, L0 >. a11d S(l~) are available. Obviously, if  flux dct>i:
the material can be considered as a
graybody over D./.., the effective emissivity        (34) a.
E'& remains equal to the spectral
emissivity e').·                                         For a blackbody, which is perfectly
                                                     absorbing, a is equal to unity. For a real
fiGURE 1. Emissive power versus wavelength.
                                                                                         Blackbody
                                                 /"T'/Mf=nif
                                           I: \
                                           I : :'"'\
                                           )<I :' \ '\
                                                                                                    Graybody
                                           I --.i .
                                    / ;·\  ,· '- '{                                                 '-...., '-....., Real surface
                                    /// \.),/ '' ~--.' "/?<.... __ _. .
                                    I '/ , / ·----, -
                                     I..'             '.· ••••...• .•..••··........-··
                                 I
                                    //
/....--··'
                                                                                                                                   ),
                                                             Wavelength
legend
   Lf = spectral radiance associated with blackbody
 Mf = spectra! (or monochromatic) emissive power of blackbody
  M:.. =spectral emissive poWN{W·m-l·pm-1)
    }. = wavelength
   Am = maximum wavelength
92 Infrared and Thermal Testing
medium, at least a small part of the         (37) p
incident radiation is reflected. Then, the      As in the case of absorption, the
absorptivity remains strictly less than      reflectivity is generally dependent on the
unity. Absorptivity a generally depends on   angular and spectral distributions of the
the angular and spectral distributions of    incident radiation. However, the angular
                                             distribution of the reflected radiation
the incident radiation. Analogously to the   must also be taken into account, leading
emissivities, spectral and directional       to defihition of more parameters: total or
                                             spectral, hemispherical, directional
absorptivities must be defined1              hemispherical, hemispherical directional
introducing four parameters: a, a', a1. and  and bidirectional reflecth•ities.
a'1,~ the first three being computable from
the latter- that is1 the directional            The fundamental quantity, specific to
spectral absorptivity:                       the sample, from which every parameter
                                             can be computed is the bidirectional
       Ia',,L1.i cos8dQ                      reflectana' distribution function (BRDF) (,1.:
(35) U.),  In                                (38) {,),
                 Lj.jCOS8dQ
                                             where dhr is the reflected radiance in a
           n                                 direction 0,(6r,lflr) and d£1. is the irradiance
                                             due to the incident radiance L1.1 in an
(36) u.'   Ja'J. L1.i d),                    elementary solid angle dQi around the
                                             direction Qi(ej,{}lj).s (See Fig. 2.)
           ),
   'lb describe now the reflection of the
incident flux by the material, its total
reflectivity is first defined:
FIGURE 2. Reflection of rad'1aflon at opaque surface can be described by defining total or
spectral, hemispherical and directional reflectivities.
                                                                                                                                              dL;_,
legend    reflected radiance in direction 0,(9, <.p,)
          surface area
  dL).r   elementary solid angle (steradian) around direction n,(O,tp,}
   dS
          elementary solid angle (steradian) around direction n,(G,,<.p,)
  dO;     incident radiance (W·m-2·sr·'·J.lm-l)
          angle (degree~) relative to normal of direction D.(fl,<.p,)
 do,      angle (degrees) relative to normal of direction H,{fl,<.p,)
          azimuth angle of direction n,(O~q:>,)
   LJJ    azimuth angle of direclion n,(O,~.p,)
   e,
   e,
 ••••
                                                                           Fundamentals of Infrared Radiometry 93
Finally, in a similar way, the           (44)
transmission of radiation by a nonopaque
material can he described by defining its    Another important relation between
total or spectral, hemispherical or          radiation properties is Kirchhoff's law if
directional transmittivities, all deriving   the material remains at local
from the bidirectional transmittance         thermodynamic equilibrium:
distribution function (BTDF) (0..
                                                 The ability of a medium to emit
    Every parameter definition has not
been given here but the actually useful      radiation at specified ·wavelength and
quantities will only be specified later.
Moreover, the reader should notice rat11er   direction is thus related to its ability to
disturbing confusions in the literature,     absorb the same radiation. This
where authors use different and
sometimes inconsistent definitions. A        fundamental property extends well
reliable reference is the monograph from
the National Bureau of Standards and its     beyond the thermal radiation domain,
considerations and nomenclature have         taking its origin in quantum physics.
been closely followed here.8
                                                Emissivity r't. and its integrals r,.. r' and
    The radiant energy conservation is       care intrinsic properties, depending only
obviously verified at any surface element:   on the sample temperature. On the
                                             contrary, a'1• is the only intrinsic
Thus, according to the definitions of the    absorptivity, because its integrals are
total radiation parameters:
                                             functions of the angular and spectral
(40) (J. + p + T ~ J                         distributions of the incident radiation.
    Neglecting any phenomenon inducing       Consequently, the total absmptil'ity is
a change in frequency, like raman
scattering or nonlinear optics, the energy   generally different from tile total emissivity.
balance can be restricted to an elementary   As an example, in solar collectors, a
spectral interval:                           maximum value of a toward solar
                                             irradiation and a minimum value of£ arc
   Searching for a relation between
directional spectral quantities, the         simultaneously required. In this case, the
scattering of radiation by the sample must   latter is total emissivity integrated over
be taken into account. Even in the case of   the spectral range of a blackbody at the
a unidirectional incident radiation, the     collector temperature whereas its total
reflected and transmitted radiation are
mostly scattered over their respective half  absorptivity is integrated over the solar
spaces. So, directional hemispherical        irradiancc spectrum.
reflectivity and transmissivity must be
used, which are defined respectively as         The radiative balance associated with
the ratios of the reflected and transmitted  Kirchhoff's Jaw brings an indirect path
fluxes over the whole half spaces to the
directional incident flux. They can be       toward the directional spectral emissivity:
expressed as spatial integrals of the
bidirectional distribution functions:        PT"" a't, = 1 ~  ~
(42) PT                                      which becomes fairly simple for an
                                             opaque material:
and
                                                                    - p').'
J(43) •T ~ fi>. case, dll1
                                             Physical Fundamentals of
                        n                    Radiative Properties
The radiative energy balance links the       As said above, according to the
directional spectral properties:             electromagnetic theory, a medium is
                                             conveniently characterized hy its complex
                                             index:
                                                The two indexes 11 and kex arc often
                                             called the optical constants of the
                                             medium, despite the fact that they are
                                             actually strongly variable with
                                             wavelength.
94 Infrared and Thermal Testing
Fresnel's formulae permit the                electromagnetic waves, which cannot
                                                propagate in such a medium.
calculation of the reflectivity as a function
                                                   Via the theoretical expression of p'J.(9),
of the indexes n and kf.'x for a                Fresnel's formulae allow the knowledge of
nonscattering medium with a perfectly           t';.. versus the emission angle. For clean
smooth surface. Reflection on such a            polished metals; c';..(9) remains constant
medium is called spewlar and leads to           till 40 degrees, then strongly increases
simplified notations:                           with a maximum beyond 80 degrees
                                                before diving back to zero at grazing
(49) PT    p'),                                 angles. Thus the hemispherical E is higher
                                                than E'11 because it integrates the higher
and                                             values of r' at large angles. Typical values
                                                for polished metals in the infrared are:
(5o) tT
                                                (54) E;, < 0.1
The emissivity can then be derived from
the radiation balance:                          and
(51)                                            (55) 1.2
where Fresnel's formulae give the specular         However, these values strongly depend
reflectivity under normal incidence:            on surface conditions: roughness, oxidation
                                                and even pollution. Roughness leads to
(52) P\    P't.n        + k"2                   more diffuse surfaces and greater apparent
                                                emissivities, increasing the actual radiance
   If this sample is sufficiently thick or its  by cavity effects. Oxidation can even
absorption coefficient high enough, there       make metals behave like dielectrics and
is no transmitted radiation:                    the emissivity of the oxidized metal
                                                generally depends on the oxide thickness.
(53) £),,  1 - Pin                              Finally, the emissivity of a metal gener(llly
                   411                          decreases toward long wavelengths and
                                                increases rather slightly versus
   If the sample surface is rough, the          FIGURE 3. Typical directional emissivities.                                   80 degrees
theoretical study is much more difficult.                                                                               1.0
                                                                          10 degrees
Many works have dealt with this problem,
leading to complex mathematical                                           0.25 0.5 0.75
developments but not to very good                                                                                 F)'.
agreement with experiment. However, the
                                                 legend
particular but fundamental case of the               a =- polished metal emissivity curve
                                                     b == lambertian surface emissivity curve
specular reflection allows the prediction            c == opaque dielectric material emissivity curve
of ty'pical radiation behaviors, mainly              d = blackbody emissivity curve
                                                    c).=- spectr<Jl directional emissivity
distinguishing two groups of media:
metals and dielectrics.
   For metals, the extinction index is
high, namely in the infrared where kex is
most often higher than 11. They are
opaque for a thickness far lower than
1 run (4 x JQ-5 in.). If k,,, is much higher
than n, p\.~1 approaches unity and r.'}.J/
approaches zero.
   Thus, in a wavelength range where a
medium absorbs very strongly (the
absorption coefficient is equal to
4nkf.'x·l.-1) it becomes almost totally
reflecting and is able neither to emit nor
to absorb. There is only an apparent
inconsistency: the absorptivity and
absorption coefficients must not be
mistaken for each other. The small
non reflected part of the incident wave is
indeed very strongly attenuated. A perfect
mirror would totally reflect the
                                                Fundamentals of Infrared Radiometry 95
temperature, apart from oxidation effect.      multiple reflections induced by the
                                               microstructure. Dielectrics can then
(See Fig. 3.)                                  appear opaque (essentially because of
   For dielectrics, the extinction index k is  scattering) over their macroscopic
                                               thickness whereas their grains remain
nearly always negligible, when compared        transparent. Such a material can present a
to 11. Then, the specular reflectivity only    strong directional hemispherical
depends on the refractive index:               reflectivity and consequently a weak
                                               emissivity: this medium may he described
(56) p',.,  (n - 1)2                           as a white body by analogy with materials
            (n + 1)2                           appearing white in the visibie·range.
   For example in the case of glass, 11 takes     The radiation behavior of gases should
a value around 1.5 in the visible leading      also be discussed because of their
                                               difference in their behavior from the
to a reflectivity value p}.11 = 0.04. For      behavior of condensed matter. The
water, the index 11 is as low as 1.33 and a    interaction between the gas molecules is
reflectivity of 0.02 is calculated.            very weak and their energy levels remain
                                               spectrally sharp. Consequently, the
   Though k remains most often                 spectral transmissivity of a gas present\ <l
negligible, the sample thickness can be        great number of quasimonochromatic
                                               spectrum lines, with spectral hanch•.:idths
sufficient to ensure sample opacity. Then:     of about J0-2 cm-1.
                                     411           All these spectrum lines correspond to
                                               rotation and vibration energy levels of
                                 (n + 1)2      molecules, to which countless translation
                                               levels are superposed. The study of gases
    Nevertheless, it is often advisable to     is thus very intricate because spectral
check the sample for opacity.                  correlation phenornena appear: the
                                               transmissivity, integrated over a large
    For opaque dielectrics, the normal         spectral bandwidth much more wider
directional emissivity can only be less        than the Jines, does not exponentially
than O.S if 11 is greater than 6, ·which is    decrease as a function of the distance.
not realistic. Emissivity E'(S) remains        Such an exponential behavior is only
constant till 60 degrees before decreasing     verified in the strictly monochromatic
to zero at grazing angles and there is no      case.
intermediate maximum as in the case of
                                                   Unfortunately, the transmissivity of gas
metals. Hence, E is smaller than £;1 and       is an essential factor in many industrial
                                               applications (for example, combustion in
typically:                                     furnaces or motors) and radiometric
                                               measurement are nearly always carried
(58) £      0.95                               out through the atmosphere. Because
                                               modeling the transmissivity of gas is very
   The influence of surface condition is       difficult, empirical formulae are
far less critical for dielectrics than for     commonly used for its computation (for
metals, essentially because the -emissivity    example, l.owtran's formula for the
values are already close to unity.             atmospheric transmissivity)Y
   The emissivity of dielectrics is often      Semitransparent Media
said to increase from near to far infrared
but dielectrics actually present more or       Radiation always travels inside a real
less numerous reflection bands. So,            medium, at least over a very short path.
dielectrics cannot be considered as gray,      Following the same idea, a sample of any
except over limited spectral intervals.        material transmits radiation if it is thin
Close to their strongest absorption bands,     enough. Thus, semitransparency appears
dielectrics often behave like metals and       as the general behavior of real media.
present typical reflection peaks, which
locally decrease their emissivity. This is         Two different mechanisms cause the
notably the case of glass at a wavelength      attenuation of radiation inside the
of about 10 ~tm, where p)J1 "" 0.3.            medium:
   Outside these absorption regions and          1. Absmpliuu corresponds to the encrb"')'
for common dielectrics, whose refractive            transfer from the incident wdiation to
indexes are close to I.S, the normal                the electrons, atoms or molecules,
emissivity values fall around 0.95 but only         yiPlding heat conduction in the
if the sample remains opaque. Indeed, at            material.
·wavelengths far enough from the
absorption bands, dielectrics become             2. Scatterins corresponds to random
semitransparent and their emissivity is             changes in the propagation direction
tlms lower.                                         because of multiple reflection and
                                                    refraction by small heterogeneities.
    Moreover, scattering inside the material
can increase its reflectivity because of the
96 Infrared and Thermal Testing
These random changes produce an                The product" ~;:I is called the optical
attenuation of the radiation propagating     · tllic:kness of the material and permits
in the incident direction: fog scatters the
rays of automobile lights and can even        quantification of the notion of
become opaque at large distances              semitransparency (for material thickness I
although water itself is transparent to       and for radiation at a wavelength /,):
visible light. The same differences are
observable at solid state between snow          1. For opaque material, P;.:l > S; then
and ice.                                           1;, ~ cxp(-P>:/) < 0,01.
   Because the elementary processes of
                                               2. For transparent material, P1:1 < 0.01;
scattering by the microstructure are very
complex, they are taken into account here          then 1,, > 0.99.
only from the macroscopic point of view.        3. For semitransparent materials,
Matter can then be considered as
homogenous again and characterized by             0.01 < p,.f < 5; then 0.01 < 1;, < 0.99.
its complex index, its absorption and
scattering coefficients and its phase         The general problem of radiation transfer
function.                                     across ari emitting, absorbing and
                                              scattering medium is rather intricate as
   The radiance losses along an               can be seen from the mathematical form
                                              of the transfer equation (Eq. 63).3.4,10,11
elementary path ds in a direction n is
                                                  The crudest approximation for
expressed in terms of the absorption K>.      one-dimensional geometry assumes that
and scattering Ot spectral coefficients:      the radiance distribution consists in two
                                              isotropic components: this is known as
   At local thermodynamic equilibrium,        Schuster-Schwarzschild approximation
the emission gain is proportional to          and leads to rather simple and easily
Planck's law at the local temperature:        interpretable results. For example, suppose
                                              a standard value of 10 crn-1 for an
(61) dL>.,e ~ K,,L0 dT(s)jds                  isotropic scattering coefficient. If the
                                              following set of values are considered for
   Besides, scattering along the path         the absorption coefficient- 0.01, 0.1, 1,
induces a radiation gain in the direction     10 and 100 cm-1 -then the values of the
Q because of scattering from all the other    bulk reflectivities are respectively: 0.94,
                                              0.82, 0.54, 0.1 7 and 0.02. The medium
directions n'. This incoming scattering is    thus appears as white (highly reflective)
                                              when its absorption coefficient is much
described and quantified by introducing a     lmver than its scattering coefficient and
biangular phase fimclion p1.(s,Q',Q):         black in the opposite situation.
(62) rlL,,ct  ~ds                                 The radiance transmitted through a
                                              macroscopic thickness l within the
              4n                              medium, as given by Bouguer's law,
                                              appears as the solution of the equation of
              x Jp,,(s,Q',n)L,,(s,n')dll'     transfer when the gain terms are omitted:
              4n                                  Within a nonscattering medium, the
                                              equation of radiation transfer is greatly
                                              simplified:
   Summing these four contributions to       (65) dL,,(s) + K,,L,,(s)
achieve a radiation energy balance along             ds
the path tis, the classical form of the         Integrating the equation of transfer
tmmfer equation is derived:                  along the thickness I gives the radiance
                                             expression at the boundary of the
(63) rlL\ (s,n) ~ -(K,, + a,)L,,(s,n)        material for the direction normal to the
                                             surf<Ke:
      '"
                                             (66) 1.,, (1) L,, (o) exp(-K,,I)
               + K}. L0},[T(s)] + -4"n'-
                                                                                I
             x JP;(s,ll',n)L,,(s,n')drl'
                                                         + K,,J LnT(s)jexp(-K,s)ds
                               4n
                                                                                0
The two Joss terms can he gathered by
letting ~A == K,. + O). be the extinction
coe{f1cienl.
                                             Fundamentals of Infrared Radiometry 97
L0 }JT(s)j is the spectral radiance of the                        typically semitransparent, apart from
blackbody at the local temperature T(s). If                       thick black paints. Effective emissivities
the material is isothermal, then IY1.!T(s)] =                     have been measured from )._ = 3 to S.S pm
L0,_(T0) and:                                                     to 0.5 or 0.6 pm for painted sheet steels.
(67) L1.(1) L1•(o) exp(-K1J)
             fI
                + K1. L? (To) exp(-K).S}ds
                                              0
                 L1•(o) exp(-K,l)
          + L? (q [1- exp(-K,I)j
   The first term, exogen, originates
outside of the medium and is transmitted
through it whereas the second term,
endogen, is emitted within the medium.
   Besides, according to the definitions of
E}. and 1").:
yielding by identification:
                   and
                                       - exp(-K;J
                       These results are obtained for an
                   isothermal medium and without
                   considering the reflections at the
                   interfaces. This can be used to evaluate
                   the spectral radiation properties of the
                   atmosphere layer between a radiometer
                   and the surface of the radiating object.
                       The semitransparent behavior of a
                   material has tv-.ro main practical
                   consequences for radiometry:
                     1. The emissivity depends on the
                        thickness of the material if the
                        material is isothermal. The emissivity
                        loses its physical meaning if there is a
                        temperature gradient along the
                        thickness.
                    2. A part of the radiance coming out of
                        the material arises from sources
                        behind the material.
                       In the short wavelength atmospheric
                   l1and (3 to S.S pm), many common
                   dielectrics such as glass and plastics
                   exhibit a semitransparent behavior for
                   material thickness up to 1 mm (4 x lQ-2).
                   This phenomenon occurs less frequently
                   in the long wavelength atmospheric band
                   (8 to 12 tJm), where the absorption
                   coefficients are stronger, but this problem
                   must still be solved especially for thin
                   submil1imeter layers. Paint coatings are
98 Infrared and Thermal Testing
PART 3. Temperature Measurements
The principles of radiometric                    The spectral radiance leaving the
measurement of temperature are well           surface of an opaque material at the
covered in the literature.t2,B                temperature 1'u is the sum of the endogen
                                              and the exogen contributions:
Equations of Radiometry                                    L (T)E}',00
                                                                 },
As mentioned above, real materials            J-t fr). L}J cosa' dQ'
present emissivities lower than unity.
Thus, a radiometer in front of an object                   n
detects not only the emitted (endogen)
radiance but also a part of (exogen)              Generally, a radiometric measurement
radiance due to the reflection of the         is carried out in air, a medium that has a
ambient fluxes by the object surface. Both    refractive index equal to unity (that is, the
contributions are then attenuated by          refractive index of air is one) but that
absorption through the atmosphere bilt        absorbs a part of the infrared radiation.
simultaneously reinforced by the emission     Consequently, air can be actually
of the atmosphere. It is necessary to take    considered as a semitransparent medium
into account these phenomena for every        and the calculation of the radiance needs
measurement purpose, especially for           the solution of the equation of radiation
objects with low temperature or weak          transfer. To simplify, air is taken here as
emissivity.                                   homogenous and nonscattering. The
                                              equation of radiation transfer becomes:
   An infrared camera measures the flux
of the incoming radiation. The                   Computing the radiance L).(s) would
radiometric signal H' measured by the         need the knowledge of the temperature
infrared camera is then given by triple       profile along the optical path between the
integration of the monochromatic              sample and the camera. Because this
radiance from the object:                     temperature profile is rarely known in
                                              actual test conditions, the radical
III(71) w ~     R(J.,n,s)LJ.(1,,n,s)dS        simplification of an isothermal
                                              atmosphere is widely used:
        1. n s
        x cose dn dl.
where R(A,Q,S) is the response of the            The complete solution of this
detection device, including the detector      differential equation is:
sensitivity, the transmissivity of the
optical device and the amplification by       (76) LJ.(s) L1.o exp(- KJ.s)
electronics.
                                                     rr+ ('I~tm)
   In most radiometric measurements, the
detection solid angle and the target             Jt must satisfy the boundary condition
surface area remain small and can be          for s ::: 0, that is, at the surface of the
validly considered as elementary. This is     sample:
not the case for the spectral interval f..A,
·which is most often taken large enough to    (77) L,.(o)     E'). L~(To)
increase the signal to noise ratio of the
device. The calculation of the signal then
contains only an integration over the
spectral sensitivity domain to..A of the
camera. Defining S(A) as the relative
spectral sensitivity, the measured signal
can be written as an effective radi<mce L:
(72) L  JS(1,)LJ. di-                                      J+ fr~. L).i cosa' dQ'
        '"                                                    n
                                                           Fundamentals of Infrared Radiometry 99
Arriving at the camera, ·where s == I, the  If the incidmt nulianceL1,1 is supposed to
radianre is L>, (/):                           be isotropic, the reciprocity and
(78) L1,(1) [L1,(0)- L~('l~tm)]                Inormation properties of frl. yield:
            x exp(-K1J)                        (83) L1,,  LA\ t;i, cos8'dl2'
                 + L}.(Tatm)                      Then, applying the radiation balanr('
                                               for an opaque material:
                L1,(o) exp(-K1J)
             + L~,(I:,.m)[l - exp(-K,J)]       The isotropic condition on the incident
                                               radiance is more especially realized in an
   from tl1is equation, the atmosphere's       isothermal enclosure. If a room can
transmissivity and its emissivity, which       reasonably be considered as isotherm£~! at
can be introduced because of the               the temperature 1~ then the radiance
isothermal hypothesis, can he identified:      incident on any object inside the room is
and                                            isotropic and equal to the radiance of a
                                               blackbody at the wall temperature. In this
                   exp( - K1J)
                                               case, the reflected radiance is simply
                                               evaluated by:
   Finally, the radiance arriving at the
camera is the sum of three terms:
(81) L1,  t> r), Lf('l~)                          This situation, leading to the simplest
                                               result, is commonly used in infrared
          t}.J+ fri.Lt.icosS'dO.'              radiometry. The isotropic condition on
                                               the incident radiance is thus included in
   Only the first term appears to be           the standard comlWuns o(rndiomelr)'.
endogen and related to the sample              Jf the incident flux cannot be supposed to
temperature. The two latter terms are          be isotropic, some assumptions should be
exogen because they represent the              made about the object surface. For <m
reflection of the ambient radiation on the     opaque object with a diffusely reflecting
sample surface and the proper emission of      surface, the distribution function is
the atmosphere. Because the atmosphere         independent of incidence and reflection
has been considered as isothermal,             angles:
homogenous and nonscattering, the last
term has been written here under a very        Then:
simple form.
                                                          JP~. L~.i cosO' dO.'
   Above, the radiance reflected by the
sample towards the radiometer has strictly     ·where E Is irradiance at surface, Lis
been expressed in terms of the                 reflected radiance, d!l is solid angle (sr), t;,
                                               is spectral emissivity, 8 is angle (degrees)
r;,,bidirectional reflectance distribution     relative to normal and p is reflectivity.
function (BRDF) and of the spatial                The irradiance E\ could be theoretically
distribution of the radiance L;.i incident
on the sample surface:                         evaluated from the experimental
                                               conditions, both geometrical
J{,(82) L,_, ~  1,L1_; cos a' elf!'            (configuration factors) and radiometric·
                                               (radiances of the different surfaces
          n                                    surrounding the object under
                                               investigation). Practically, the quantity
   Generally, neither frA nor LH are knmvn     Ei..·n- 1 can be evaluated by measuring the
and the reflection term must be simplified
with respect to practical applications.
Simplifying assumptions must be made,
concerning either the incident radiation
or the reflection properties of the surface.
100 Infrared and Thermal Testing
radiance reflected by a rather good difftlse     (91) L
surface (such as a crinkled aluminum foil).
                                                            I+ *h. (1- e',)L~('l;,)dA
r;,,Ideally, for a perfect diffuser: E). = 0, =              I"'·
1·111 and L!.r = E>:rr---1•                                 + s(1.)(1 - ,·,. )Lnr.,,m) r11,
   For a perfectly specular surface, the
                                                                   ,\1,
distribution function is zero except for the
direction symmetrical to the measurement
direction and can be expressed by means
of Dirac's delta function. Then, the
integration reduces to:
where Lts is the incident radiance in the           This intt'gral relation is the actual
spewlar direction. This radiance can he          (tmdamental equation ofradiometry.
simply calculated from the sole part of the      llowever, strong theoretical difficulties
surroundings situated in the symmetrical         appear if it is attempted to keep a rather
direction relative to the normal to the          simple expression for the detected
specular olJject. Practically, the radiance      radiance. Effective radiation properties
L1,\ can be measUred ·with a quasi perfect       over the device sensitivity range must be
mirror (gold, silver, aluminum) for which        used. For example:
t'1, = 0 and then LAr = L>.s· Ideally, in the
general case, a perfectly reflecting replica     (93) '"'·   I s(<)r',.E}J~(To)di,
of the real surface should be used.                          I""·
   It is useful to return to the main                              s(l.) L?, (To) di,
problem of the radiometric measurement
as a whole. Through a nonscattering                            "'·
isothermal atmosphere at the temperature
Tatm with transmissivity t'1• in the                        I s(l,)t',.L?,(1~)di,
measurement direction, the radiometer                       IA).
actually receives:
                                                               S(I,)L?.(To)dA
(89) L,, <), [r)J,f(To)
                                                              A).
      + [r,,. r,.; cos8'dn']
                                                    These effective properties depend on
           + (1 - t).)Lf(I:,.m)
                                                 the temperature and are consequently not
If the surroundings can be considered as
isothermal at the temperature '/~, the           the same at Tm T..1 or 1~tm· Furthermore,
spectral radiance takes its standard form:       e;.neither S(k), nor the Planck's intensity,
(90) L,,  "'>.e\L~ ('/~)                         nor and particularly t}. are constant
                                                 over the interval/1/,.
          + 1',(1 - e',.)L~('I~)
                                                    Let£ be the effective emissivity of the
                                                 material under investigation and the
                                                 effective transmissivity t of the
                                                 atmosphere over the sensitivity range of
                                                 the device. Usually, the material is
                                                 supposed to be gray over IJ.),,
                                                    Transmissivity tis practically evaluated
                                                 with semiempirical formulae or tables 12
                                                 and is taken to be unity at the calibration
                                                 distance. \'\'ith these assumptions, the
                                                 standard equation is finally obtained:
          + (1 - t' >J L~ ('J~tm)                (94) L     Tf.L0 (T0 ) + t(1-E)L0 ('J~)
   As mentioned above, the spectral                         + . (1-t)Lo(Tatm)
interval/1/.. is most often taken large
enough to increase the signal~to~noise              This relation, sometimes called the
ratio of the device and cannot be validly        fundamental equation ofradiometty, is
considered as elementary. According to           commonly used to derive the temperature
this, the expression of Li, written above        T0 of the material from the metlsurement
must be integrated over the spectral             of the radiance L. (See Fig. 4.)
sensitivity range of the device (essentially
that of detector and optics):                       Many assumptions have been necessary
                                                 to derive this quite simple exprt>ssion, so
                                                 that the accuracy of the temperature
                                                 measurements depends on the validity of
                                                 these assumptions in the actual
                                                 measurement situation.
                                                            Fundamentals of Infrared Radiometry 101
Practical Remarks                                        small ·windows are available. Sapphire,
                                                         fluoride or silicon \Vindows are used in
Nonoxidized metals can reasonably be                     the short wave domain, whereas for the
considered as gray and opaque. On the                    long wave domain windows are made in
contrary, for many dieft>ctrics the gray                 zinc selenide or germanium. Less
assumption is more especially doubtful in                expensive windows can be realized using
the short wavelength range, ·where they                  thin plastic foils (e.g., most polymers for
are semitransparent, transmissivity 1),                  short wavelengthsi polyethylene for long
being neither zero nor constant in this                  wavelengths).
range.
                                                            Because windows are never full
   Variations ofF-'>. due to selective                   transmitters, at least because of reflection,
reflection (variation of p}, with I~) often              the attenuation of the infrared flux
occur in the long wavelength range for                   through these windows must be taken
dielectrics (e.g. the reflection peak of                 into account. At calibration distance,
ordinary glass around 10 pm). In this                    without window, the infrared camera
case, restricting the wavelength sensitivity             receives the radiance L from the object at
range with a filter can help select a                    temperature ~):
limited domain of constant (and if
possible higher) emissivity. However,                    (95) L
using a filter \VOU!d reduce the received
infrared flux and is only of interest when               where f is the object effective emissivity
hot material makes the infrared emission                 within the ·wavelength domain of the
strong enough.                                           camera.
Measurement through                                         Through a \Vindow of transmissivity tw,
Windows                                                  this radiance is attenuated by a factor tw:
                                                         Additionally, the infrared camera also
A current problem is to measure the                      receives both the radiance reflected from
temperature of a surface through an                      the ambient by the window and the
infrared window, e.g. samples under                      proper emission of the window. Finally,
controlled atmosphere or in a vacuum.                    the camera measures the radiance I:
Otherwise, it can be necessary to protect
the camera from an aggressive                            (96) L  Tw£L0 (To)
environment- for example, hot gas
flows.                                                           + Tw(l-e)L"(J;,)
    Unfortunately, almost perfectly                              + Ewl0 ('~.,,) + PwC'(Ta)
transparent windows within the
wavelength domains of infrared cameras                      It must be pointed out that the
(short wave 3 to 5.5 pm, long wave 8 to                  window properties tw, fw, Pw are generally
14 pm) are very expensive and only quite
FIGURE 4. Standard radiometric measurement configuration. Temperature 70 of materia! is
derived from measurement of radiance L where effective atmospheric transmissivity t of over
sensitivity range of device is unity at calibration distance.
                  Isothermal environment                 <(1-<)!,(TJ ~}
~<)L'(T,)
                                  Isothermal atmosphere  tEL0 (T0) ~
                                                         (I - t) L'(T,~) ~
      " Object surface at T0
legend
     L0 = blackbody radiance (W·m-2·sr-1)
     T~ = temperature of isothermal surroundings (K)
 Tatrn =atmospheric temperature (K)
   =T0 object temperature (K)
      r: = effective object emissivity
      t = effective atmospheric transmissivity
102 Infrared and Thermal Testing
not constant over the sensitivity             On a blackbody at a temperature T
bandwidth of the infrared camera but       close to Tw, the transmissivity for the
depend on the wavelength. Consequently,    ambient radiation is simply given by:
the transmissivity of the ·window depends
on the spectral distribution of the        (103) 'w         L - L0 (1~\')
considered infrared radiation coming                       L0 (T) - L" ('1;,)
from the sample. A window which is
more transparent at shorter -wavelength       Hereafter, the transmissivity for the
than at longer wavelength within the       radiation coming from a bhlCkbody at a
camera bandwidth would be globally         temperature close to ~. can be
more transparent for radiation from a      determined:
higher temperature source (compare
Planck's law):                             (1 04) Two      L- (1- Tw)L"(T,,)
(97) Two *- lw                                                   L" (To)
because:
          J*h,wL~.(T0 )di,                 Radiometer Calibration
(98) Two  f~~-                             It is very difficult to determine the
             s(ic)L~ (I;,)dic              spectral sensitivity of an infrared
                                           radiometer such as an infrared camera.
          "'·                              Consequently, the link between the
                                           effective blackbody radiance and the
whereas:                                   blackbody temperature cannot be
                                           established by integration. Furthermore,
          f S(ich.wL~ (T,)di,              the sensitivity varies with time and a
                                           calibration is necessary, at least once a
"'·f(99) Tw    s{lc)L~ (T,)dic             year or when the detector or an electronic
                                           component is replaced. During such a
          "'·                              calibration procedure, the correlation
                                           between the temperatures and the
   h\-\1 en the sample is at a notably     radiances L0 (1) is experimentally
different temperature from the ambient,    established using a laboratory blackbody,
the window transmissivity Two for the      situated at the calibration distance /0 from
sample radiation differs from its          the camera. The measured radiance Lis
transmissivity tw for the ambient          then:
radiation:
(1 00) L  Two EL" (7~)                     f(105) L
          + Tw (1- e)L"(I;,)                               S(i,)T\L):(T)dic
          + (1- Tw - Pw)L"(Tw)                         f"'·+ s(!c)(l - T',,)L~ (T,m)di,
          + PwL0 (1;)                                  "·
If the \Vindow temperature T... is near
ambient temperature T3 then this
equation can be simplified:
(101) L
The values of the window transmittivities
Two and Tw can be determined by
measuring through the window the
radiance coming from a blackbody (c = 1)
at the corresponding temperatures:
(102) L
                                                           Fundamentals of Infrared Radiometry 103
f(106) L to S(A)L~ (T)di,
        f&
         + (1 - t,.,) s(i,)L~JT,.,)dA
                                                    A),
    Effective atmospheric transmittivities at
the calibration distance I ::: 10 are taken to
be equal to unity and the correlation
between temperature and radiance of the
blackbody is then simply given:
f(107) L ~ L0 (T) ~ S(I.)LnTJdA
                 "'·
   To minimize calibration differences due
to atmosphere variations, the calibration
distance is taken as small as possible,
generally /0 < 1 m. Moreover, the aperture
of the blackbody must be seen under an
angle sufficiently large to avoid
underestimation of the measured
radiance, because of diffraction
phenomena.
    In practice, the radiometer stands in
front of a laboratory blackbody and the
radiance I is expressed in arbitrary
customer units. It is measured for each
optical configuration as a function of the
blackbody temperature, then a calibration
curve is determined, fitting the
measurement points by a function of
three variables (say, A, B and C). Because
the physical response of the radiometer
·would be Planck's Jaw in the
monochromatic case, the fit is generally
taken of an analogous form:
(108) I ~  A
    Even when the radiometer is calibrated
in arbitrary units, radiance I is
nevertheless proportional to the radiance.
The standard equation of radiometry
remains verified in arbitrary units:
(109) I    tEio + t(l - £)I,
         + (1- t)I,1m
Closing
The relationships described above govern
the 'Nave behavior of infrared radiation
and can be used for the scientific
description of radiometry.
104 Infrared and Thermal Testing
References
                    I. Born, M. and E. Wolf. Priociples uf
                        Optics. London, United Kingdom:
                          Pergamon Press (1959).
                     2. Stone, j.M. Radiation and Optics. New
                          York, NY: MacGraw Hill (1963).
                       3. Siegel, R. and J,R. Howell. Thermal
                        Radiation Heat Transfer. New York, NY:
                          MacGraw Hill (1972).
                    4. Ozisik, M.N. Radiative Transfer and
                        Interactions with Conduction and
                       Convection. New York1 NY: john Wiley
                          (1973).
                     5. Hottel, H.C. and A. F. Sarofim. Radiative
                       Transfer. New York, NY: MacGraw Hill
                          {1967).
                     6. Sparrow, E.M. and R.D. Cess, Radiation
                        Heat Transfer. \.Yashington, DC:
                        Hemisphere Publishing Corporation
                          (1978).
                       7. lncropera/ P.I. and D.P. De Witt.
                        Fundamentals ofHeat and Mass Transfer.
                          New York, NY: john \\Iiley and Sons
                         {1981).
                      8. Nicodemus, F.E., ).C. Richmond,].].
                          Hsia, I.\'\1• Ginsberg and T. Limper is.
                       Gem1wtrical Considerations mul
                       Nomenclature for Reflectance.
                         Monograph 160. Gaithersburg, MD:
                          National Institute of Standards and
                          Technology [\·Vashington, DC:
                          National Bureau of Standards] (1977).
                    9. Airborne Visible/Infrared Imaging
                       Spectrometer (AVIRIS): Airborne
                       Geoscience H'orksl.wp Proceedings.
                          Pasadena, CA: California Institute of
                          Technology, Jet Propulsion Laboratory
                          (2000).
                   10. Chandrasekhar, S. Radiative Trans{e1~
                          New York, NY: Dover Publications
                          (1960).
                   11. Kortiim, G. Re{lectallCe Spectroscopy.
                          Berlin, Germany: Springer-Verlag
                          (1969).
                   12. Hudson, R.D. Infrared System
                       Engineering. New York, NY: john Wiley
                          and Sons (1969).
                   13. De\'\'itt, D.P. and G.D. Nutter. Tllemy
                       and Practice ofRadiation Thermometry.
                          New York, NY: VViley-lnterscience
                          Publications (1988).
                                                                                                                 Fundamentals of Infrared Radiometry 105
.' .
.I
                                       CHAPTER
     Noise in Infrared
        Thermography
          Nik Rajic, Defence Science and Technology
          Organisation, Melbourne, Australia
PART 1. Definitio111, !Effects and Measurernent
The term noise refers to any spurious or       where k is Boltzmann's constant {\V·s·K~ 1 ),
unwanted signal in a system.' Because all
measured signals are affected by noise, it     Tis absolute temperature (K), R is
is essential to have some understanding of
the origins and properties of noise. This      electrical resistance (n) and d{is
chapter describes the various types of
noise that arise in infrared thermography      bandwidth. It .will be noted that johnson
and the techniques for quantifying the
                                               noise increases with respect to both
noise.
   In the broadest sense, noise falls into     temperature and bandwidth.
one of two categories: random or fixed         Generation recombination noise occurs
pattern. Noise can also be classified
according to whether it impacts on a           in semiconductor materials (involving
signal in either an additive or a
multiplicative sense. In general, random       most photon detectors) and is caused by
noise is usually additive, meaning that the
magnitude of the random fluctuation is         fluctuations in the rate of generation of
independent of the signal intensity, ·whilst
fixed pattern noise is most commonly           free charge carriers1 produced by the
multiplicative, as in the specific case of
detector sensitivity variation.                incident photon stream and of the
Random Noise                                   recombination of oppositely charged
Random uoise, known also as stochastic         carriers. It tends to have a flat pmvcr
noise or uncorrelated noise, is characterized
by a signal whose value at any particular      spectrum up to a frequency that
position or time is independent of values
that precede or follmv. By definition          corresponds to the free carrier lifetime
therefore, it has no deterministic
description but can be described by \Vay       and declines rapidly ·with further increase
of certain statistical properties. Random
noise can arise from a variety of sources      in frequency.
that mostly relate to the detection system.
In tl1eory, the radiating object and its       The mechanism that generates {-1, or
surroundings can also contribute random
signals through fluctuations in the            excess noise, is somewhat more
emitted photon flux but these variations
tend to be very small compared to those        mysterious with its underlying
that occur in the detector system. \'\7ithin
the detector, the process of transforming      mechanism not well understood. Possible
the incident photon flux to an electrical
signal can involve at least three              theories have been proposed2 and
fundamental mechanisms of noise
production: johnson noise, generation          evidence suggests a dependence on
recombination noise and £-1 noise.
                                               semiconductor processing.3 The noise
   Johnson or thermal noise (also known
as nyquist noise) occurs in all conducting     exhibits a power spectral density that
materials and is a consequence of the
chaotic or random motion of free               varies inversely with frequency, hence its
electrons. The root mean square voltage
produced by this noise is: 2                   name, and is significant only at low
(1) ~'nns                                      frequencies. Figure 1 provides an
                                               illustration of the noise spectrum for
                                               torr-'these detector based sources. As shown, it
                                               is usual       noise to dominate at the
                                               lower end of the spectrum,
                                               generation/recombination noise in the
                                               midrange and johnson noise at higher
                                               frequencies.
                                               The three noise types discussed thus far
                                               relate to the process of transforming
                                               incident photon flux into an electrical
                                               signal. 1v1odern infrared imagers usually
                                               convert this electrical signal into a digital
                                               FIGURE 1. Spectrum of primary semiconductor noise sources.
                                                         J-1 nolse dominant
                                                                           Generation and recombination
                                                                                                  johnson noise dominant
                                                                    -- • • . . - - - - --- ~c,---
                                                              Frequency (log scale)
108 Infrared and Thermal Testing
equivalent through a process known as          instances of each possible value, the
                                               resulting curve is bell s}laped ~ typical of
digitization. This leads to another source     a gaussian or normal ct\stti_bttll?D .•
of noise called quantizatio11 noise, which     (Fig. 2b). Note that the distribution is
arises whenever an analogue value is           discrete because the intensity at each
converted to a discrete level. The amount      pixd is represented by an eight-bit
                                               number and thus has only 256 possible
of quantization error fntroduced depends       values (and the subtraction result had
on the quantization level. Given a true        been rescaled around 128). A gaussian
value v that is converted to a digitized or    distribution is commonly assumed when
quantized value of vq, the variance            describing the properties of noise in
introduced by quantJzation error is: 4         infrared systems. As Fig. 2h suggests, the
                                               assumption is often very good but the
          +.il2l:                              possibility that some noise processes may
     - J (v -1 I'  2                           produce nongaussian noise should be kept
(2)            '1                              in mind. For a continuous random
     ~1'           v, ) d1'                    variable x the gaussian distribution has
          v _Al_
                     1                         FIGURE 2. Image containing random noise: (a) difference
                                               image; (b) histogram showing underlying normal
          "'                                   distribution.
     -1 (M)2
     12                                        (a)
where Llv is the quantization increment.
This shows that the quantization error
falls as the quantization increments
decrease, as might be expected. In the
limit of a continuous representation
(lw = 0), the error vanishes.
Fixed Pattern Noise                            (b)
Fixed pattem noise or correlated noise refers        15
to noise having a distinct pattern. In an
imaging context, such noise may appear
in the form of an object distortion (barrel
or pincushion), although this is
uncommon in modern optical systems.
Intensity variations are a far more
common type of fixed pattern noise.
These can be caused by mechanical or
optical vignetting, noticeable by a reduced
irradiance toward the periphery of the
image, or by sensitivity variations
between detectors in a focal plane array. It
is interesting to note that because humans
are quite adept at perceiving patterns,
fixed pattern noise tends to be more
noticeable to the observer than an
equivalent amount of random noise.
Measurement of Noise
Noise is characterized by its probability
density function, which in essence defines     0 10 f--------
how often a particular value of the
random variant is observed. The
probability density function can be
estimated by forming a histogram of the
noise population. For example the image
shown in Fig. 2a ·was formed by
subtracting two thermal images of a static
scene, acquired using a 512 x 512 focal
plane array infrared camera. It will be        0 L___ll        .,,    I,
noted that the image is not completely                                                         II-
featureless but contains :-:.light intensity     0             100
variations produced by the random noise                             150 200 256
sources discussed earlier. If a histogram of
the image is formed by counting the                                 Gray level
                                                               Noise in Infrared Thermography 109
the following prClbability density                              cameras is the noise equivalent temperature
function:                                                       diffi'rt'IIC£'. This parameter represents a
                                                                measure of the signal-to·noise ratio
(3) p(x)                                                        evaluated in relation to the temperature
                                                                of the viewed object. 1n effect it defines
where p is the mean and cr2 is the                              the temperature change that a viewed
variance of x. It will be noted that these                      ohject must undergo for the change in
two parameters completely describe tl1e                         signal power to exceed the power of the
distribution. The gaussian distribution has                     system noise.
a number of use.ful properties ~ for
example, averaging N separate
measurements of a signal containing
gaussian noise leads to a reduction in
noise level by a factor \IN. (This effect is
not restricted to gaussian distributions.)
Other useful properties are discussed
elsewhere.:l
Signal-to-Noise Ratio
The signal-to-noise ratio (SNR) is defined
as the ratio of the signal power to the
noise power. By providing a measure of
the system noise relative to the proper
signal it yields a useful indication of the
true significance of the noise. Maldague5
describes a procedure for evaluating the
signal-to-noise ratio for a thermal
inspection system. Given a static scene,
two images are captured successively in
time. Designating these as A and B, t11e
signal-to-noise ratio is simply:
(4) SNR  _!_~'Mal_
where:       2
                    and
                  Here, i and j index respectively the x
                    and }' directions in an image of N x A,f
                    pixels and J-1 is the mean of the noise
                    distribution E. \Vith this definition the
                    signal-to-nOise ratio depends on the scale
                   used for A and B. The result varies
                   according to whether A is expressed in
                    units of Kelvin or degrees celsius.
                        ~vfanufacturers often define the
                   sensitivity of an instrument based on its
                    intrinsic signal-to-noise ratio. A related
                   measure specific to infrared imaging
110 Infrared and Thermal Testing
PART 2. Noise Reduction thrrough Image
Processing
All image acquisition systems are             system configuration. Given a scene with
susceptible to noise processes. By            uniform brightness and ~1ssmning a linear
implication it follows that all images will   detector response, the process is to
contain some noise. Even those that           acquire an image at each of two knmvn
appear entirely satisfactory when observed    intensity levels and to then write Eq. 7 for
casua1Iy will invariably betray perceptible   each case. Because only two unknowns
levels of noise when exposed to more          are involved these equations me easily
exacting scrutiny. The levels at which        solved:
image noise is considered significant is a
subjective matter that depends entirely on    (8) Ai,i   li/2 -Iijl
the usc to which the information is                       Sz -Sr
applied. Whereas the image quality
furnished by modern infrared detection        (9)
apparati would satisfy most
thermographers, such data may appear             Any scene is then recoverable by
exceptionally noisy when exposed to           means of the following operation:
machine interpretation where sensitivity
to noise is vastly more acute than that       s(lO) 1,;  I;,; - B;,;
possessed by the human observer. The                         Ai,J
trend toward automation in concert with
the growing imperative for quantitative          The most notable disadvantage of this
interpretation should ensure the              simple approach is a high sensitivity to
continued relevance of image processing       noise. This arises from the division in
as an important means of noise                Eq. 10 by a distribution A that tends to be
suppression for thermographic                 rather noisy if evaluated as suggested.
applications. Processing techniques           Note in particular the escalation of noise
effective in this regard are described        implicit in Eq. 8, which is caused by the
below. The treatment given here is            subtraction of two uncorrelated noise
necessarily brief, so in the event that       distributions. A simple means of
more detail is required, the reader is        improving robustness is to form the
directed to texts on the subject.6            images 11 and /2 based on a temporal
   To facilitate discussion of image noise,
it is helpful to adopt the following simple
model for the image formation process
illustrated diagrammatically in l'ig. 3:
                                              FIGURE 3. Image composition process.
                                                                                    £(x,y)
·where the subscripts i and j respectively    8S(x,y)                               t          t(x,y)
index the horizontal and vertical position
of pixels in the image. For a given scene       legend                              E8
radiance S, degradation of the image I            A -= gain factor
occurs through the random noise term £             8 -= offset factor               I
and through distortion (nonuniform                 1 =image
distribution) of gain factor A and offset B.       S = scene radiance                  B{x,y)
                                                   x = first dimension
Fixed Pattern Noise                               y =second dimension
                                                   £ = noise term
Its inherent stability makes the removal of
fixed pattern noise a relatively
straightfonvard exercise. Equation 7
implies that if the distributions of A and B
can be characterized then the sceneS is
recoverable hy mathematical substitution.
A simple experiment can be devised to
determine both parameters for a particular
                                                                        Noise in Infrared Thermography I I 1
average (recall that for N frames the noise                  Here, the constants Care estimated by
variance diminishes by a factor N if the                  least squares. Figure 4 shows a fixed
noise is gaussian). It may however be                     pattern gain aberration pertaining to a
impractical to perform the average over a                 512 x 512 focal plane array camera,
period sufficiently long to yield a                       evaluated by least squares.
satisfactory noise reduction. In such cases
an alternative approach is to prescribe A                    Another alternative is to apply linear
and R functional forms and to fit these to                regression independently to each pixel.
the noisy distributions. A biquadratic                    Because Eq. 7 describes a straight line the
function usually suffices, particularly if                task of estimating A and B is equivalent to
the pattern derives from an optical                       estimating the slope and intercept of a
distortion:                                               linear regression model. To best exploit
                                                          the inherent noise rejection advantages of
(11) A(x,y)  Ctx2 + C 2 j12 + C3X)'                       the least squares approach, the pixel
                                                          response needs to be sampled many times
             + C4x + CsJ' + C6                            for a given excursion of the scene
                                                          radiance. To this end, a peltier cell is quite
FIGURE 4. Gain aberration for 512 x 512 pixel focal plane array infrared camera: (a) from
unaveraged pair of frames; (b) from averaged pair (30 frames); (c) biquadratic fit shown as
contour plot with raw data included for comparison.
(a) (b)
                     (c)
                                    200
            " 150
                        ~
               e"'
                       8
                         0
                                                      ·~
                                 c
                          21
                              c 50
                                        0
112 Infrared and Thermal Testing
useful in providing a scene with the           Instead, if the scene variation is
                                               sufficiently repeatable, as is often the case
requisite spatial uniformity and variable      in _pulse thermography, averaging may he
                                               applied on a synchronous basis. This
radiant intensity.                         !   involves capturing many image sequences
                                               of the same dynamic scene, which are
It should be noted that contemporary           then averaged to produce a single cleaner
                                               sequence. This approach entails additional
infrared systems apply corrections for         experimental burden, requiring either the
                                               ability to perform real time processing or
pixel sensitivity variations as part of a      the means to store and later to process
                                               copious data.
standard internal calibration procedure.
                                                  More often than not, however, a
These corrections rely on internal             dynamic scene is effectively m•ersampled,
                                               that is, acquired at a rate higher than the
reference flags to help determine pixel        minimum necessary to preserve important
                                               temporal information, which permits
sensitivities for a particular configuration.  frame averaging to be applied within a
                                               sequence. The process is called box car
However, these corrections apply only to       twerasins and the kernel is defined:
effects inherent to the detector and
cannot therefore account for fixed pattern
noise of optical or mechanical origin.
Some focal plane array cameras correct for
nonuniformity of AiJ and B1;·
Random Noise                                   (12) jk  2v + 1
Random noise is principally dealt with by      where k is frame index. The width 2v + 1
using smoothing or filtering. Each             of the averaging window dictates the
involves a process whereby a                   degree of smoothing. The selection of an
measurement is moderated according to          appropriate value for v involves a
some prescribed, usually linear, operation     compromise between the degree of noise
on neighboring values. Such operations         rejection required and the amount of
can be applied in either the temporal or       smearing that is tolerable. The same
spatial domain, however a preference will      consideration applies in the practical
usually emerge based on an assessment of       context of setting the infrared detector
the required outcome and the nature of         integration time, equivalent in effect to
the data. Because most filtering               the window length of a moving temporal
approaches cannot distinguish between          average. Indeed, an understanding of hm\'
noise and true signal, the need to preserve    the moving average works is found hy
signal integrity in a particular domain        considering the frequency response
often establishes this choice. If for          function of a simple integrator:
instance temporal fidelity cannot be
compromised, filtering is best applied         <BJ r    J'
with respect to the spatial domain and
vice versa.                                                exp(-i wt) dt
Temporal Averaging                                      t=O
Temporal averaging was briefly discussed                - 1-[l- exp(-ion)]
as an effective means to improve the
robustness of gain and offset distortion                 iCJH
characterizations. Of course, the principle
applies equally well to the routine            Here, ro is the circular frequency (rad·s-1}.
treatment of image noise. The principle is     Note that the integration time 1 (second)
restated thus: for random gaussian noise       is equivalent to filter window length. The
with unit variance, averaging N frames of      magnitude of this complex function gives
an image sequence reduces the noise            the attenuation response:
variance lJy a factor N. It is quite common
in thermal imaging for the scene to be            This expression suggests that the
dynamic, that is, to change as a function
of time. The rate at which these changes       attenuation of an integn-1tor increases as
occur relative to the rate at which a frame    both a function of (1) and T, with complete
sequence is acquired is important in
deciding 'iVhat type of averaging to apply.    rejection of frequencies satisfying
A static scene is the simplest case to treat   (1) = 2n:n·r1 and 11 = 1,2,1 .... This latter
as frames in a time sequence differ only in    characteristic is undesirable from the
the distribution of random noise. As such,
all frames can be averaged to form a           viewpoint of hath detector integration
single image with noise variance reduced
proportionally to the sequence length.
   \-\7here a dyn<lmic scene is involved,
each frame is representative of a unique
scene state and thus an ad hoc averaging
of <Ill frames is obviously inappropriate.
                                                        Noise in Infrared Thermography 113
and filtering, particularly if the null         attenuated in a fashion analogous to low
response coincides ·with an important           pass filtering.
signal frequency. Although unavoidable in
the COTlft'":t r_lf detector integration, this     The smoothing effect of a low pass
                                                filter is characterized by its frequency
behavior can be averted in a moving             response function, which defines the
                                                variation in signal attenuation as a
average approach by applying appropriate        function of spatial frequency. Below are
weightings to the elements in the kernel.       described the more common variants of
More will be said of this in discussions on     this type of filter.
spatial filtering.
                                                   If the emissivity field has a high
   Cross correlation provides another           frequency content, spatial filtering is
means for achieving noise reduction in          impractical~ for example, in
the temporal domain, an approach that is        thermography of electronic cards.
often referred to as phase locked
thermography when applied to the                Box Filter (Neighborhood Averaging). Box
nondestntctive evaluation context. This         filtering, also known as neighborhood
technique is described in more detail           awraging, is the spatial equivalent of box
elsewhere· in this book. It essentially         car averaging in the temporal domain.
involves comparing the measured pixel           Smoothing is achieved by replacing each
response to a time varying harmonlc             pixel value with the arithmetic average of
thermal excitation applied to the subject       its neighbors. The average for pixel i,j is
under examination. The response at the          given by:
excitation frequency is extracted by
performing a cross correlation between             Figure Sa shows the computational
the excitation signal (which may be             molecule for a 3 x 3 box filter. For the
available as a lamp voltage, for instance)      most part, such averaging is effective and
and the detector response at each pixel.        simple but there are situations where the
The calculation can be applied in real
time or off line, though storage                FIGURE 5. Example of 3 x 3 box filter: (a) convolution mask;
requirements for the latter may become          (b) frequency response function.
prohibitive for a long sequence. Assuming
zero phase difference between the               (a)
reference and detector signals, the
amplitude of the pixel response at the
excitation frequency can be written thus:
(15)
'ivhere L is the reference signal.                            0.111 0.111 0.111
   The longer the correlation proceeds U1e                    0.111 0.111 0.111
                                                              0.111 0.111 0.111
greater the extent of noise rejection. As
with conventional averaging, noise              (b)
variance diminishes in proportion to
increasing N.                                   '0
                                                -~ 0.8
Spatial Filtering
                                                'E"
Smoothing is a process of low pass
filtering in which features of high spatial     .0s
frequency are attenuated or rejected
entirely \\'hercas those of lower frequency     .,~
are passed largely unaltered. Fundamental
to its success is the presumption that          "0
discarded frequencies pertain principally
to the image noise and are thus irrelevant      il
to the scene. This, of course, can only be
the case if the scene and emissivity field      "';;~o
are band limited, a situation not
uncommon when a thermal scene                   Frequency fy  -1.0 -1.0                          1.0
involves a process of heat diffusion. It        (normalized)
should be recalled that temperature                                              Frequency f~
gradients are an impetus for heat                                                (normalized)
diffusion, which acts to suppress these
gradients. The consequence of this is that
high frequency contributions are
114 Infrared and Thermal Testing
approach can lead to unsatisfactory                                         where the bottom half of the image has
                 results. This shortcoming is apparent                                       been filtered using neighborhood
                 when the frequency response function of                                     averaging. A comparison between the top
                 the filter is examined closely (Fig. Sb).                                   and bottoril halves illustrates the potential
                 Rather than a progressive increase in                                       for spurious amplitude and phase
                 attenuation with frequency, the box filter                                  behavior.
                 exhibits a harmonically modulated
                 response that implies irregular attenuation                                    The practical implication of these
                 across the frequency spectrum. The                                          effects are probably greatest in the context
                 behavior can be examined in more detail                                     of the inspection of composites. Figure 8
                 by ·writing the one-dimensional frequency                                   shows a thermogram derived from a flash
                 response directly from Eq. 14:                                              inspection of a woven composite
                                                                                             laminate. The image is noticeably
                 (17)    A(J..,a)  ~  _2_n!a:_  vrL;rl-'(1--  cos  A2                        degraded by noise and is a good candidate
                                                                    "")                      for smoothing. Hy deliberately choosing a
                                                                                             poor filter length, equal to the weave
                 where "A is signal wavelength and a is filter                               FIGURE 8. Woven composite subject
                 length.                                                                     inspected by flash thermography: (a) raw
                                                                                             image; (b) 15 x 15 box filter image.
                    '"'hen the function is plotted against
                 the ratio of these two parameters (Fig. 6)                                  (a)
                 the filter is observed to have a null
                 response at window lengths equal to
                 integer multiples of the signal wavelength
                 {a= n),, 11 = 1,2,3 ...). Furthermore, the
                 phase is also periodic and wraps from -n
                 ton for a= O.S·(2n + l)A, 11 = 0,1,2,3 ....
                 This behavior can lead to spurious effects
                 if the filter length is not chosen carefully.
                 Figure 7 shows an image with a linear
                 frequency swept intensity variation,
FIGURE 6. Frequency response function of one-dimensional
box filter.
             f ·--~~-    ----~~--                                  2.0
                                                                   16
          10 -Magnitude                                            12                        (b)
          0.9
                                                                   0.8
"o;- o.8j                Phase
                                                               "'.s0.4
!;(
~ 071                                                             0 ::\
                                                                                 ro
·E 0.6 r
                                                                 -0.4 ~
-" I                                                                                      ~
.1; 0.5
                                                                 -0.8
 ~        oA Ii                                                  -1.2
c"0                                                              -1.6
-~                                                                -2.0
                                                              4.0
"':r:;o;  031
          0.2
          l_,0.1
          0
              0 0.5 10 1.5 2.0 2.5 3.0 3.5
                 Normalized frequency o.).-1
                 FIGURE 7. Box filter of length a applied to image with variation in linear frequency A.
                         0.5 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0
                                                           Normalized filter length a-),-1
                                                                                                                Noise in Infrared Thermography 115
pattern wavelength in this case, some                where the standard deviation a of the
                    scene information has been lost. However,            distribution controls in concert with the
                    because the woven pattern has been                   mask size the extent of filtering that
                    removed, visibility of the four                      occurs.
                    discontinuities is enhanced. A
                    discontinuity having the size of one                     It is to be noted that the frequency
                    weave pattern would practically disappear            response function (Fig. 9) is generally
                    - the price of detecting faint and huge              monotonic. However, spurious behavior
                    discontinuities.                                     akin to that of the box filter can arise if
                                                                         the value of standard deviation a is small
                        It should be noted that a less expensive         relative to the mask size. In the case of
                    camera with few pixels can obviate spatial           the woven composite example, the
                    filtering. Spatial filtering should be               performance of the gaussian filter is
                    considered an occasional remedy.                     shown (Fig. ] 0) to better preserve the
                                                                         weave pattern (in case it is needed).
                    Gaussian Filter. Ry weighting each pixel in
                    the mask equally, neighborhood averaging             Butterworth Filter. It should be noted that
                    ascribes as much importance to the pixel             the filters discussed thus far have been
                    value being replaced as to any other                 designed by prescribing the convolution
                    member in the mask. Experience suggests              mask. In fact, a more sensible approach is
                    however that the relationship between                to prescribe the transfer function first,
                    pixel values diminishes with increasing              bec<mse it determines the filters'
                    separation. The gaussian filter                      performance, and to then seek a
                    accommodates this by weighting pixel                 convolution mask with the necessary
                    contributions according to a gaussian                characteristics. The butterworth filter
                    distribution centered about the pixel i == 0,        (Fig. 11) is created using this approach. Its
                    j = 0:                                               transfer function is:
                                                                         (19) H(fx,fj.) ~  1
                    (18) il(i,j)  ·2 ·2)N                                                  1+(r(f,,!J)2"
                                  rr                                                       r,,
                                   M        p  (  -~
                                  ex              2cr
                                  j,] jo;J                               where:
FIGURE 9. Example of 3 x 3 gaussian filter: (a) convolution              (20) r(f, f)·)
mask; (b) frequency response function.
                                                                         where r is tile distance from the origin
(a)
                                                                         and f0 denotes the wavelength (cutoff
                      0.057 0.124 0.057
                    0.124 0.272 0.124                                    FIGURE lO.Thermal image of woven composite filtered with
                                                                         15 x 15 gaussian kernel (cr = 3).
                    0.057 0.124 0.057
(b)
'@ 1.0
.':!
" 0.8
E
s0 0.6
w
u 0.4
·icl
      0.2
eron
:;;
      0
      1.0
      Frequency /r  -1 -1                                           1.0
      (normalized)
                                                  Frequency fx
                                                  (normalized)
116 Infrared and Thermal Testing
value) where the attenuation of the filter     cases ·where an image is interspersed ·with
                     has fallen by 50 percent.                      large amounts of binary or shot noise,
                                                                    characterized by either a null or saturated
                         The order of the filter 11 controls how    pixel value. Because such values carry no
                     steeply the filter transitions through the
                     cutoff value. As 11 gets very large the        FIGURE 12. Test image: (a) unfiltered; (b) ideal low pass
                     transition approaches a discontinuous          filtering; (c) second order butterworth filtering.
                     step and the filter begins to behave like an   (a)
                     ideal low pass fHter by passing largely
                     unattenuated all frequencies below the         1.0
                     transition and rejecting entirely all
                     frequencies above. The term ideal refers to    0                   X
                     the shape of the transfer function and not
                     to its practical functiona1ity. To the                          y
                     contrary, the step transition is to be         (b)
                     avoided because it can lead to a
                    phenomenon known as ringing, one of the         1.4
                     principal reasons why the ideal low pass       1.2
                     filter is rarely used. The effect is shown in  1.0
                     Fig. 12.                                       0.8
                                                                    0.6
                     Median Filter. The box, gaussian and           0.4
                   butterworth filters rely on a convolution        0.2
                    process and are thus classed as linear          0
                    filters. In contrast the median filter relies
                     on a nonlinear operation. Instead of
                     calculating a weighted smn of values
                     within a prescribed neighborhood, the
                     median filter replaces the central value
                     ·with the median of the population. By
                    depending on a ranking operation, the
                     median filter is particularly useful for
FIGURE 11. Second order butterworth filter: (a) convolution
mask; (b) frequency response function.
(a)
                     0.063 0.125 0.063
                 0.125 0.250 0.125
                                                                         y              X
                                                                                        X
                 0.063 0.125 0.063                                  (c)
(b)                                                                 1.0
                                                                    0.8
'0' 1.0                                                             0.6
r.o~ o.s                                                            0.4
                                                                    0.2
E0 0.6                                                              0
.s               ~1 -1                                   1.0
(]) 0.4                             Frequency t~
                                    (normalized)
-o
·E0 o.z
;"'!' 0
       1.0
   Frequency fy
  (normalized)
                                                                                        Noise in Infrared Thermography 117
FIGURE 13. Thermogram showing composite    useful information the best approach i~ to
delamination: (a) image contaminated with  remove them from the image, which is
binary noise; (b) 3 x 3 median filtering;  what median filtering is designed to
(c) 3 x 3 box filtering.                   achieve. Figure 13 illustrates comp"r,llive
(a)                                        effects of median filtering and
                                           neighborhood averaging for an artificially
(b)                                        degraded thermal image of an impact
                                           damaged composite plate. Whereas
                                           averaging merely smears t11e shot noise
                                           over the filter length, median filtering
                                           discards the offending values and also
                                           better preserves sharp detail in the image.
                                           (Note in particular the fiber indications
                                           that run diagonally across the image.)
                                           Harmonic Filter. As stated earlier, the
                                           efficacy of low pass filtering depends
                                           largely on the assumption that scene
                                           information is biased toward the low end
                                           of the image wave number spectrum.
                                           However, given specific knowledge of the
                                           underlying phenomenological process
                                           from which the measurements have
                                           evolved, it is possible to design a filter
                                           that is more selective regarding the
                                           frequency components that are attenuated
                                           in uniform emissivity and absorptivity
                                           fields. An example is the harmonic fi1ter 7
                                           designed to filter measurements known to
                                           arise from a harmonic process1 that is,
                                           from a process governed by Laplace1S
                                           equation:
(c)                                        Equation 21 describes heat diffusion
                                           under steady state conditions and
       -- ..-                              consequently the harmonic filter is
                                           potentially useful in thermographic
                                           applications. The filter \Vorks on the
                                           a,principle of constrained optimization.
                                           Given a noisy function a function II j~
                                           sought that minimizes the following
                                           relationship over a prescribed domain:
                                               JJ ;~ ) ~~2 2
                                           (22) ( + ( ) dx d)'
                                           subject to the following constraint:
                                           (23) NMs2   NM
                                                      2.; 2.; [u(x,,n)
                                                      h=O j-""0
                                                      ''(x,,)'jlf
                                           ·where s is a smoothing tolerance and N
                                           and M define the grid size.
118 Infrared and Thermal Testing
PART 3. Techniques to Increase Emissivity
Emissivity E is defined as the fraction of    Surface Coating
power emitted at a given temperature
(and in a given spectral range) relative to   The energy emitted by an object radiates
that of a blackbody at the same               from a surface layer only 3 or 4 pm (about
temperature. It is expressed as:              1.5 x lQ--4 in.) thick.1 In dielectric
                                              materials the distance can be a thousand
(24) E).                                      times greater. Consequently, it can be
                                              asserted that emissivity is principally a
where E). is the result of an integration     surface property. \¥here access to the
                                              target object is unrestricted, an effective
over 2rr steradians and where h ~- is         means of enhancing its emissivity is to
                                              coat the surface with a high emissivity
radiant emittance of a blackbody, defined     paint. This practice is commonplace in
by Planck's Jaw:                              thermographic nondestructive testing and
                                              in thermoelastic stress analysis. As well as
(25)                                          ensuring high emissivity such coatings
                                              have the added benefit of producing a
                               exphe--- 1     uniform finish, a factor often important
                                      HT      in nondestructive testing where emissivity
                                              variations complicate the task of
and where Ais ·wavelength (meter), Tis        discovering concealed structural damage.
temperature (K), cis speed of light (m·s-1),
fi is Planck's constant and k3 is                 It is worth noting that a paint may
Boltzmann's constant (\oV·s·K-1).             need to satisfy more than just the sole
                                              criterion of high emissivity. If the paint is
    Emissivity ranges in value from unity     likely to impact adversely on the
for a perfect emitter (a blackbody) to zero   functionality of an object and cannot
for a nonemitter. In relation to thermal      remain in place after inspection,
imaging, high emissivity is critically        important to restoring the object to its
important for two key reasons. Hrstly, it     original state is that the paint be easily
promotes enhanced radiant emittance and       removed. To this end, water based carbon
so assists the remote infrared detection      suspensions are finding widespread usage,
process by improving the signal-to-noise      in preference lo solvent based paints,
ratio. Secondly, it implies low reflectance   particularly in aerospace applications
(p = 1 - e) thus reducing scope for signal    where existing surface finishes have a
corruption by reflected emittance from        specific functional purpose and need to be
extraneous sources. Spurious reflections      preserved. Such paints are also Jess likely
are a serious hindrance to the proper         to react chemically with most materials.
interpretation of thermographic data. For     As a general rule, the compatibility of the
example, reflectioilS causing erroneous       chemistries of the paint and object should
temperature measurements could, in a          be verified.
condition monitoring exercise, initiate
costly supplemental inspection or trigger         It is important not to draw inferences
unnecessary preventive maintenance.           about the infrared emissivity of a paint
                                              based purely on its color as perceived by
   Applications like nondestructive testing   the human eye. Although most paints
are also susceptible. For instance, it is     promoted on the basis of efficient heat
entirely possible to mistake a localized      radiation are black, it is erroneous to
reflection for an indication of structural    assume that only and all black paints
damage. Broader reflections are equaJiy       have high emissivity. V\1hite titanium
disruptive by potentially obscuring actual    dioxide paint, for example, has an
discontinuities that can be imaged under      emissivity of 0.94, surpassing that of
more favorable conditions. This all serves    many black paints on the market. A
to underscore the critical importance of      reliable source of data or advice should
ensuring that object emissivity is high.      always be consulted before judging the
The following discussion provides             suitability of a particular paint.
guidance on how this may be achieved
and points out relevant factors to consider       Paint is by no means the only
when choosing an approach.                    compound capable of producing a high
                                              emissivity finish. Puwder is a possible
                                              alternative, although adhesion and spatial
                                              Noise in Infrared Thermography 119
uniformity are likely to be inferior to 'that  where x = L;          '' [r., - T,)
of paint. Powder in practice is
uncommon. Liquid latex is reportedK to                 -k iJTP
have good emissivity and has the               (30) P dx
attraction of easy removal once cured.
Another option is to apply adhesive tape.      where x =a;
It should be noted however that tape is
likely to have a more significant impact       (31)  k    uT      k aT,
on the measured thermal response than                              s Ox
paint and may thus demand more                         p  _axI '
diligence in the interpretation of the
measurements.                                  where x = n;
Response Modification Due to                   (32) Tp(.t,O)      0
Surface Coating                                where l = 0;
                                               (33) 7~(x,O) ~ 0
Surface coatings change more than just
the emissivity of an object. They also         where t = 0. ln Egs. 26 to :u, Tis
inevitably modify the manner in which a
structure responds to a thermal stimulus       temperature (K), Q(x,t) is pawer density,
and may thus have an important bearing         k is thermal conductivity, o: is thermal
on the interpretation of the thermal           diffusivity, 11 is the interfacial thermal
response measurements. The extent to
wl1ich such an effect needs to be              conductance, subscript Ji refers to the
considered in practice depends on factors
such as the thermal properties and             paint layer and subscripts refers to the
relative thickness of the object and its       substrate.
coating, as well as on the use to which
the response measurements are applied.            The temperature response to a pulsed
                                               excitation of duration t0 and intensity QH
    In general the effect of a coating ranges  absorbed at the surface x = 0 is given by:
from insignificant in the case of relatively
thick objects made of low diffusivity          FIGURE 14. Two-layer slab of indeterminant width.
material, to quite substantial for an article
comprised of thin aluminum. For the
most part, the effect is far more
pronounced in the transient regime than
under quiescent thermal conditions and is
therefore most relevant to active
thermography of m.etallic objects.
Consequently further discussion of the
issue is confined to pulsed thermography.
The prospective effect of a coating can be
examined by studying the heat diffusion
equation for a two-layered slab (Fig. 14) as
defined by the equations:
      o2T.
       ,
.i(26)         +   I  Q· p(x,t)
                  -k
        uX p
where 0 < x = a, and:
(27)
where a< x < L, with the following
boundary, interface and initial conditions:
(28) -()Tp     ~0                              legend
        dx                                       a "'paint thickness (arbitrary unit)
                                                 L =substrate thickness {arbitrary unit)
where .x = 0;                                    x =dimension normal to part surface
(29)  ()Ts        0
      dX
120 Infrared and Thermal Testing
(34) T(x,t)                                   objective is merely to fmd a discontinuity;
                                              (2) quantitative, where a discontinuity is
where:                                        detected and then.characterizcd. From the
                                              effect iiJustrated in Fig. 15, a coating is
(35) l        for 0 < t :5: t0                unlikely to reduce the prospect of merely
              fort0 <f<=                      detecting a hidden structural
                                              discontinuity- except where the
and                                           diffusion time across the discontinuity
                                              diameter {in substrate) is shorter than the
(36) Q = {~0  for 0 < t :5: fo                diffusion time through the coating. On
              fort0 <f<oo                     the contrary, emissivity equalization
                                              rendered by a properly applied coating
and where the quantity p11 satisfies the      may assist detection by excluding
                                              reflection as a tangible cause of an
transcendental equation:                      indication. The scenario is quite different
                                              in quantitative applications, primarily
(37) 8tan(p,a) + tan[yp,(L-a)] = 0            because of the delay effect mentioned
                                              above.
and where the quantity 3 is expressed as
follows:                                          It is instructive in discussing this
                                              matter further to focus on the contrast
(38) E        zplla +sin2Pn X)                response, that is, the deviation in
                                              response at a suspect site compared to
                   4P,                        that from a sound reference. Such
                                              contrast curves form the basis for most
   Before considering practical case          quantitative approaches to thermographic
                                              nondestructive evaluation. Figure 16
studies, it is important to note that a       illustrates such a response for a case study
coating of about 10 to 30 pm (0.4 x J0-3      involving a coated 1.6 mm (0.06 in.) plate
to 1.2 x lQ-3 in.) in thickness is necessary  with a 0.8 mm (0.03 in.) deep void
                                              discontinuity. Conventional practice
to obscure a polished metal surface with      would see the discontinuity depth
paint applied by aerosol. Under normal        estimated on the basis of the time taken
field conditions, the urge to avoid missing   for a characteristic event to occur in the
a spot may lead an inexperienced              contrast curve. The time to peak contrast
technician to the deposition of even          and the time to contrast inflection
heavier coatings. Figure 15 shows the         (stationary point of the first time
                                              derivative) are good examples. Figure 16
response preclictecl by Eq. 34 to flash       shows the delay induced in the contrast
heating of a 10 mm (0.4 in.) aluminum         response by t11e presence of a coating and
                                              from this the potential for a biased depth
plate (1) when bare and (2) when coated
with acrylic based paint. The curves          FIGURE 15. Surface response as function of layer thickness for
derived for the coated structure suggest a    acrylic paint as predicted by Eq. 34 for 10 mm (0.4 in.) thick
three-stage response comprising               aluminum plate.
successively: (1) an lnitial regime
dominated by the coating; {2) a transition               Aluminum           10'   10'
                                                            reference  Time (ms)
phase where the response involves
heterogeneous behavior; and (3) a steady      1o-'
period of substrate dominated lJehavior.             10- 1
The delay of the substrate response
induced by the coating is the key effect in
terms of impairing quantitative analyses.
Note that this delay, even for relatively
thick coatings, is quite short in any
practical sense, which implies that only
objects that exhibit relatively fast
transients are likely to be affectt>d,
aluminum being a good example.
   Active thermography is applied in two
distinct forms: (1) qualitative, where the
                                                                       Noise in Infrared Thermography 121
estimate if the delay is not considered.                        are made with respect to the visible
                           Indeed, a coating may render any                                spectrum, the issue of emissivity becomes
                           estimate of discontinuity depth virtually                       irrelevant. Absorptivity, however, remains
                           impossible it, as shown for the 55 p.m                          ari issue in tests using optical energy.
                           coating, the curve is shifted beyond values
                           that can be explained by the presence of a                         There are, as with all techniques,
                           discontinuity alone. This underscores the                       limitations and disadvantages. Paints and
                           importance of ensuring that coatings are                        films have an inferior temperature
                           made only as thick as required to produce                       resolution and limited dynamic range
                           a high emissivity finish.                                       compared to modern infrared photon
                                                                                           detectors. And, as with all coatings, they
                           Thermochromatic Paint or                                        disturb heat flow through the article and
                           Film                                                            consequently yield a biased temperature
                                                                                           response, as discussed above. Films in
                           A thermochromatic substance changes                             particular have rather slow response times
                           color in response to a change in                                and are thus unlikely to be suited to roles
                           temperature. Someone unfamiliar with                            where thermal event times are very short.
                           the effect need only visit the local toy
                           store where toys can be found that                              Surface Modification
                           undergo changes in color when clasped in
                           the hands or dropped into a bucket of                           Surface modification is another means of
                                                                                           achieving a useful increase in emissivity.
                           cold or hot '''ater. The past decade has                        Table 1 lists the emissivities of several
                           seen the advent of thermochromatic                              common metals for a variety of different
                           paints and thin films that offer                                surface preparations. A polished finish
                           temperature sensitivities suitable for                          consistently yields the lowest emissivity.
                           application to a wide range of thermal                          Indeed, polished metal can serve as an
                           inspection problems. By translating a                           excellent infrared mirror and there are
                           change in temperature to a change in                            many examples of such usage. An abraded
                           color these materials offer a very low cost                     surface has higher emissivity, due in most
                           alternative to conventional thermal                             part to the cavity effect described below.
                           inspection techniques that require                              Nevertheless, the emissivity of an abraded
                           expensive thermal imaging apparatus.                            surface remains quite low, to the extent
                           Importantly, because the measurements                           that abrasion has relatively little practical
                                                                                           benefit; at an emissivity of 0.2 a surface
FIGURE 16. Effect of painting on contrast evolution calculated                             reflects four times as efficiently as it emits
for 1.6 mm (0.06 in.) aluminum skin with 50 percent                                        and is thus vulnerable to stray reflection.
material loss.                                                                             Oxidation and anodizing are chemical
                                                                                           processes that result in the deposition of a
          1.0     ... - .... ...f-- -· / l.--;:·                                           compound that typically has higher
                                                  r-        .~··                           intrinsic emissivity than its parent metal.
~ 0.9             .-                                                                       If permitted on functional grounds,
                                            . r-·- ~-         · - ·: -                     promotion of oxidation is quite an
c         0.8              i . +-i- c-;~ - r-~-~-                                          effective way of raising emissivity to
                                                                 - 1-                      useful levels.
~
"'.-.ee~  0.7              .I                               r-- - ···-
          0.6
                           -.~ --r ·---; f-- -·             r--- 1- --
c~ 0.5                                                 -·                                  Table 1. Emissivlties for common metals.
                           -'-... I_                                                    -
                                                                                                Material Surface Finish Emissivity
·.,R-0
~                               · - ~.   -   -   -· - 1--
11<ii     0.4                                    1-- · · - - · - ··-
"~        0.3              ..L :-.;~ - 1--       - f---1--1- 1--                           Aluminum  polished          0.04
                                                                                                     sandblasted       0.21
.~                           I                                                             Brass     anodized          0.55
                                                                                           Copper    oxidized          0.11
§ 0.2          -  '1---;-  ~-   f"-  '-- 1-                                                Steel     polished          O.Q3
                                                                                                     abraded           0.20
!/ r.-z0 0.1         --;· - . -             -- · -f - f---  1---1--                                  oxidized          0.61
                                                                                                     polished          0.02
                  /                                                                                  heavily oxidized  0.78
                                                                                                     polished          0.02
          0                                                                                          oxidized          0.69 to 0.95
                  5 10 15 20 25 30 35 40 45 50 55 60
                                            Time (ms)
   legend
        • = 27 111n coating)
      " =55 prn coating
     -- =uncoated
     ----=uncoated, 3 percent materia! loss
122 Infrared and Thermal Testing
Reflective Cavity                               fiGURE 17. Conical shaped reflector.
Pyrometry
\.Yhcn the radiant emission from a small
opening in an isothermal enclosure is
examined, the spectral response is found
to closely approximate that of a
blackbody. This Cat'il)' effect applies to all
materials and enclosure geometries as
long as the opening is sufficiently small.
Reflective cavity pyrometry is a means of
exploiting this effect to overcome low
emissivity problems. Figure 17 sho'\\'S a
conical reflective cavity positioned above
a low emissivity object. The observed or
apparent emissivity as inferred from the
radiant flux through the fiber bundle may
be substantially increased by judicious
selection of the emissivity and geometry
of the reflector, as ·well as the standoff
distance to the object. In a noncontacting
approach, some clearance needs to be
maintained between the reflector and
object. The clearance limits the extent to
which blackbody conditions can be
approximated. Nevertheless, given
prudent reflector design high emissivities
arc achievable. Various aspects of reflector
design have been examined in the context
of online temperature measurement
during sheet metal fabrication.9 The
approach is fundamentally limited to spot
temperature measurement and cannot be
applied in any conventional way to
thermal imaging.
                                                Noise in Infrared Thermography 123
PART 4. Techniques to Overcome low Emissivity
Emissivity is arguably one of the most            (40) R).,).,
important properties in determining the
viability of a thermographic inspection.                                     exp--h-e --I
An unprepared metallic surface usually                                    ~ --"-),"oz:.:_k_:_T__
can be dismissed out of hand because it                                 /q exp--l-ie --1
reflects far more efficiently than it emits
and any data obtained are thus likely to                                              A1kT
be heavlly contaminated by
environmental emittance. As discussed                 Figure 18 illustrates the principle. It
above, however, low emissivity is easily          should be noted that Eq. 39 relates only
remedied by means of an appropriate               to radiant emittance and as such the
surface modification, most conveniently           treatment cannot account for reflected
by application of a thin layer of paint.          emittance arising from low emissivity.
Although widely practiced, cases do arise         Recall that the emittance from a
where this simple treatment is not viable.        nonblackbody comprises not only its
Possible reasons are the need to preserve         radiant emittance but also the reflected
an existing surface finish for some               emittance, the strength of which wiJl
functional purpose or a simple case of            depend on the object reflectance and the
object inaccessibility. In either situation,      surrounding environment (transmittance
alternative treatments to the low                 is negligible for most engineering
emissivity problem wi1l need to be                materials). The dual band approach is
considered. The present discussion                used mainly for hot surfaces (several
outlines inspection techniques as well as         hundred degrees celsius). Therefore, where
postprocessing techniques that offer              a dual band approach is prescribed it is
useful solutions where direct surface             important that the potential for reflection
modification is not feasible.                     !Je minimized as far as practical. Note also
                                                  that a ratio approach in general implies
Dual Band Thermography                            increased sensitivity to image noise as
                                                  discussed above.
Dual band thermography is a useful
technique by which to account for spatial         FIGURE 18. Photon emittance at T ~ 298 K (25 °C ~ 77 of) for
variations in object emissivity. The
principle is simple. The spectral photon          blackbody and graybodies with emissivity E :::o 0.8, 0.5 and
emittance of an object with emissivity £ is
given by:                                         0.2. Ratio of emittance at wavelengths /q and ),2 is identical
                                                  for each curve.
          2nc 1
(39) Q).  £;, }4                                  '0
                                  llc
          ' exp ------ I                          w
                                  AkT             .~ 1.0                                                    £ = 1.0
                                                  "E'                                                          f = 0.2
                                                  .0s 0.8
   The emittance is a function of both            cwv                                                      · - ji
temperature and emissivity. For a                 ~ 0.6
graybody, emissivity is constant with             Ew                     8 10 12 14 16 18 20
respect to wavelength. This constancy
suggests that tl1e ratio of emittance             c    0.4
measured at two independent
wavelengths (hence the term dual baud)            ~
should he independent of object                   -C
emissivity and consequently a function             Q_
only of temperature. To illustrate the
principle, consider a pair of                     'c•6 0.2
monochromatic measurements taken at               g~
the wavelengths 1~1 and 1..2• Graybody                  0           '··
behavior implies that Eu :::o LJ.z, so the ratio  w
of the emittances is:                                             46
                                                   Q_
                                                  ~
                                                               2
                                                                         Wavelength (IJm)
124 Infrared and Thermal Testing
Thermal Transfer Imaging                                  state. The function is especially useful
                                                          ,...,hen inspecting scenes cluttered with
Thermal transfer imaging is an                            irrelevant features (objects in the
experimental methodolot,ry that aims to                   background) and where only a relatively
provide a reliable means by which to                      small region is likely to respond to the
inspect low emissivity objects. The                       stimulation. Recall that the radiant power
principle is to transfer the temperature                  of an object as measured by a detector
distribution of the target object to a host               comprises two components:
structure of superior emissivity thus
providing an improved platform for                        (41) J ~ £10 + (! -c) I,
thermal imaging. Figure 19 illustrates a
possible experimental configuration. A                    The radiant emittance 10 is caused by
low conductivity transfer material is                     thermal stimulation; the environmental
usually recommended to promote                            radiation Je is reflected by the object.
persistence of a transferred thermal
image.s Such materials reduce the loss of                     Pulsed stimulation will cause those
signal intensity that occurs in the delay                 segments of the object with high
between completion of a transfer and                      emissivity to emit a higher signal than
image capture. The need to establish                      those segments that are highly reflective,
physical contact limits the practical                     thus generally improving the contrast
application of transfer imaging to cases                  within those features. To illustrate the
where this is both permitted and feasible.                potentia) for improved contrast and to
Accordingly, production line settings                     highlight important limitations, a test
where objects undergo motion along a                      case was developed using a rectangular
prescribed path are well suited to this                   titanium specimen with a narrow channel
approach.                                                 milled into the back face. The surface was
                                                          prepared with a uniform coating of matte
Reference Image                                           black paint followed by the application of
Subtraction                                               three thin strips of gold paint known to
                                                          be reflective in the infrared band. The
Useful reductions of the appearance of                    article was inspected by means of pulsed
emissivity artifacts as ·well as other                    thermography in the arrangement
background effects may be achieved by                     indicated by Fig. 20. Thermograms
subtraction of an image taken of the
object in a quiescent state, sometimes                    FIGURE 20. Experimental arrangement at mome~t of flash
called a reference image. Such an operation               discharge. Specimen size is exaggerated for clanty.
serves a similar role to the calibration
button found on many infrared imagers.
Its role is to affect relative radiance
measurements with respect to a reference
FIGURE 19. Illustration of transfer imaging arrangement.
                   Heat slnk  line heater
Transfer medium
/
Object
                                                          Noise in Infrared Thermography 125
obtained before and after excitation arc   inspection process. Specifically, the time
shown in Fig. 21. Subtraction of the       history at each pixel location is
reference from the response (Fig. 22a)     transformed to a complex fou~j_er
shows noticeably improved contrast for     spectrum by:
the material loss indication but also for
the reflective strips. Other approaches    where the phase at each frequency u is
involving normalization are possible.5 In  given by a relationship between the
general the reference will need to have    imaginary and real parts of F11:
both offset and contrast adjusted to
account for the difference in average      (43) $,      Imaginary IF;,l
temperature compared to that of the
excited response (Fig. 22b).                        atan Real lr.,l
Pulsed Phase                                  The insensitivity of a phase map to
Thermography                               emissivity variations is partly explained
                                           by the fact that a surface feature,
An object with an irregular emissivity     providing it is thermally thin, has no
distribution will give rise to a thermal   means by which to affect the time history
image containing corresponding intensity   and consequently the phase distribution
variations. These can mask underlying      of a thermal event in the substrate. A
discontinuities and generally serve to     phase map is actually sensitive to
unnecessarily comp1icate interpretation.   absorptivity variations, which are often
Pulsed phase thermography10 is an          correlated ·with emissivity variations. A
effective means of removing such           mathematical interpretation is that
artifacts, as well as other background
effects. The technique is based on a
temporal fourier transform applied to an
image sequence acquired during an active
FIGURE 21. Thermograms (average of 40 frames each): (a) quiescent; (b) response to pulsed
illumination.
(a) (b)
126 Infrared and Thermal Testing
emissivity behaVes likC a multiplicative     Computation of
constant and is effectively cancelled        Reflections
through division of the in-phase and
quadrature components in Eq. 43.             \-\'here the measured radiant power of a
Figure 23 shO\\'S hmv a phase map can        low emissivity object comprises a large
reduce surface emissivity artifacts and      component of reflected radiation, it may
thus clarify the presence of underlying      be possible to account for and eliminate
surface features, in this case a thickness   this component provided the emissivity
variation.                                   distribution of the object is measurable
                                             and the environmental radiation field is
Selection of Detector                        known. Jn relation to a
Spectral Band                                microthermographic application, a
                                             procedure has been used to measure the
Objects are sometimes encountered that       reflectivity of an object by using a time
exhibit a wavelength dependent               modulated infrared source and an infrared
emissivity. These are termed colored or      detector tuned to the excitation
selective emitters. For such objects, the    frequency. 11 The apparatus is scanned
radiant spectral emittance curve differs in  over the surface to form a
shape to that of a blackbody in that local   two-dimensional map of the reflectivity
maxima may appear at wavelengths where       distribution. }!or an opaque object,
the emissivity is high. VVhere a local       Kirchoff's Jaw permits emissivity to be
maximum is found to occur within one of      inferred from reflectivity, which provides
the common detector operating bands          a basis for decomposing the apparent
(3 to 5 pm or 8 to 12 pm) common sense       radiant emittance into a part stemming
suggests that the detector be selected on    from self-emittance and a part arising
the grounds of peak spectral emittance.      from reflection. Radiant emittance Ic must
                                             be known.
FIGURE 22. Improved discontinuity contrast through reference subtraction: (a) subtraction of
image in Fig. 21 b from image in Fig. 21 a; (b) as in Fig. 22 but with prior adjustment of
contrast and offset of reference image.
(a) (b)
                                             Noise in Infrared Thermography 127
fiGURE 23. Artifact reduction by use of phase mapping: (a) as in Fig. 21 b; (b) phase image
                       calculated from time sequence of 40 frames.
                     (a) (b)
128 Infrared and Thermal Testing
References
 1. Hudson, R.D. Infrared System                11. Chen, Z.H., ·c Uchida and S. 1vfinami.
    Engineuing. New York, NY:
                                                     "Emissivity Correction in Infrared
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 2.jamieson, ].A., R.H. McFee, G.N. Plass,          Vol. 11, No.1. London, United
    R.H. Grube and R.G. Richards. Infrared          Kingdom: Elsevier Science, for the
    Physics and Engineering. New York, NY:          International fvfeasurement
    McGraw-Hill (1963).                             Confederation (March 1993): p 55-64.
 3. Burke, M. YV. Handbook of.Machine
    Vision Engineering: Vol. 1, Image
   Acquisition. London, United Kingdom:
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 4.]ahne, B. Digital Image Processing.
    Berlin, Germany: Springer-Verlag
    (1991).
 S. Maldague, X.P.V. Nondestructive
    Evaluation o(Materials by Infrared
    Thermosraphy. London, United
    Kingdom: Springer-Verlag (1993).
 6. Lim, J. S. Two Dimensional Signal ami
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    Prentice-Hall Signal Processing Series
    (1990).
 7. Grundy, I. SMOOFF- A Fortran
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    ARL-STRUC-TM-490. Melbourne,
    Australia: Department of Defence,
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    Organisation, Aeronautical and
    1v1aritime Research Laboratories (1988).
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    R.P. Stout. "True Temperature
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    United Kingdom: MCB University
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    M. Lamontagne. Reflecting-Cavity IR
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    Spherical, Conical and Double-\Vedge
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    p 186-201.
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                                                Noise in Infrared Thermography 129
CHAPTER
Errors in Infrared
    Thermography
Terumi lnagaki, Department of Mechanical
Engineering, lbaraki University, lbaraki, Japan
Katashi Kurokawa, NEC San-ei, Kodaira, Tokyo, Japan
PART 1. Sources of Errors
Introduction                                  ANSI/ASivJE standard, discussed below. 1
                                              The source of errors are considered and
Infrared thermography is a convenient         calculated. The confidence levels or
nondestructive test method that can help      uncertainty levels are addressed by
visualize and estimate various                analyzing respective error strata
two·dimensional temperature fields            pertaining to the measurement process,
simultaneously by sensing                     classifying the error factor with several
electromagnetic energy emitted from           error strata.
target surfaces. Increased recognition of
the technique's app1icability has                The American Society for Testing and
prompted development of remote sensing        Materials has issued several standards for
diagnostics for various engineering           dealing with c;-rrors.2-5
applications. Infrared thermography has
been applicable across many engineering          There are many types of infrared
disciplines such as discontinuity             thermographic systems possessing
detection, condition monitoring and heat      different types of sensing and scanning.
transfer measurement. The technique can       The present chapter involves a typical
also be applied to critical diagnostics such  system using a single sensor element and
as those in nuclear facilities ·with high     mechanical scanning. A similar approach
                                              can be used for elements with multiple
radioactivity.                                sensors.
    Although infrared thermography has
                                              Definitions
t11ese convenient features, it is normal for
                                              Below, a minimum detectable size and a
the measured data to include an error in a    noise equil'alent temperature difference are
                                              referred to affecting the resolution of the
way similar to other techniques, such as      infrared thermographic system. Each
thermocouple measurements. However,           cause affecting the resolution is evaluated
the quantitative error of the measurement     quantitatively. Previous discussions of
has been difficult to evaluate precisely      qualitative measurements and
and systematically- not only in high          evaluations6,7 did not fully quantify the
temperature conditions but also in            causes. Not only the noise equivalent
conditions near ambient. It is necessary to   temperature difference (NETO),
develop quantitative infrared                 representing minimum detectable
thennography further for various              temperature difference, but also the
engineering applications by analyzing the     minimum detectable size (MDS) are
confidence level of data through an           important performance indicators of the
appropriate evaluation technique. In          infrared thermographic system and
particular, the accuracy might decrease       express the smallest resolution that can be
when applying the technique to near           detected. r:or instance, when the surface
ambient conditions, because the radiation     temperature of a target below the
energy detected at an infrared sensor,         minimum detectable size is measured, the
which is usually used for determining          shape cannot be discerned whereas the
temperature, will always include nois!' for   surrounding energy also enters the
instance from the reflected energy             detector as a noise signal, giving rise to
incident in the surroundings. For various      error in judging a thermal index measured
engineering disciplines, a quantitative        with the infrared thermographic system.
basis of infrared thermography needs to
be established that is (I) applicable to          The thermal index is composed of
ambient conditions and (2) accurate and        pixels representing radiance temperature.
 free of significant error.                    The minimum detectable size for the
                                               infrared thermographic system used for a
    This chapter analyzes the sources of       medical infrared imaging is rated with
errors in infrared thermography and then       respect to a japanese standard.H According
 discusses the calculation and evaluation      to the rating, the size threshold is
of errors. Factors of minimum detectable       calculated from the separately
 size and noise equivalent temperature         distinguishable horizontal resolution.
 difference are fundamental in                 Thus, the rating is adequate for the signal
 maintaining thermographic measurement         output to be recognizable. This definition
 confidence. Furthermore, measurement          may be suitable for applications where it
 uncertainty can be evaluated by using         is necessary merely to judge the shape of
 uncertainty analysis based on an
132 Infrared and Thermal Testing
the image hut for visual gaging and          value indicates better temperature
quantitative temperature measurement
the definition needs to clarify the          resolution of the system. \Vith respect to
relationship between the detectable target
size and the thermal index. It is also       the noise equivalent tempera!ure             .
important to clarify the rC'Iationship
between the detectable temperature           difference, a japanese industnal standardH
difference and the thermal index. The
sources of the error pertaining to the       has already been published for medical
infrared thermographic system will be
explained below with the help of an          infrared thermographic systems. The
alternative definition.
                                             standards define that the signal to
Factors Impairing
Performance                                  determine temperature is obtained from a
In general, any type of measurement          signal ·waveform as displayed by
includes errors due to a number of causes.
The infrared thermographic system is no      deflection modulation of temperature
exception, and quantitative evaluations
from multiple aspects are required to        signal and that the noise is obtained from
clarify the measurement accuracy. There
are many factors impairing the               a peak-to-peak value of noise voltage NJlP'
performance indices of typical
mechanically scanned infrared                The noise for this case is defined to
thermographic equipment. Two factors
used to describe and compensate for          be the peak-to-peak value of
errors are the minimum detectable size
(,MDS) and the noise equivalent              J"'pp X l/(2·2"·5) ~ NJlP/(2·2°·5).
temperature difference (NETD).                  However, because the noise depends on
   The minimum detectable slze is a          frequency components of the signal
primary index of the infrared
thermographic system's spatial               waveform, the procedure, in which the
resolution.9 The smaller value indicates
better spatial resolution of the system in   peak-to-peak value of tile signal W(lveform
measuring the temperature of a target
\urface on the display screen. VVhen         is multiplied by 0.2 to 0.1 1 is sometimes
measuring temperature quantitatively,        applied to calculate noise ~qu!v~lent
identifying minimum detectable size is
important. Also needed is darificatio!1 of   temperature difference. It IS difficult for
the relationship between the target SIZe
and its temperature reading. This point is   this technique to determine noise
significant for quantitative discussion of
lens aberration, diffraction effects,        equivalent temperature difference ..
amplifier frequency response and defocus
as major factors impairing the               quantitatively, bec(luse personal readmg
performance indices of the typicat
mechanically scanned infrared                errors and the frequency components of
thermographic system. The detrimental
effects of other causes of errors are        the signal waveform affect it. There is a
negligible: aperture iris refraction,
nonuniformity of temperature                 Jack in objectivity of the data measured-
distribution on a target surface and (in
some cameras) internal reflections.          the measurements are simult.:meously
   The noise equivalent temperature          affected by the sensor's sensitivity and by
difference is also the primary index of the
infrared thermographic system. 10 This       its time response. Noise equivalent
index indicates the temperature resolution
and shuws the minimum detectable             temperature difference is therefore defined
temperature difference appearing on a
target surface whose emissivity E is nearly  by calculating a standard deviation of
equal to 1.0. In other words, it is defined
as a temperature change !!Ts such that the   thermal index distribution when a
signal~to-noise ratio of the infrared
thermographic system becomes 1.0 when        standard blackbody furnace maintained at
measuring the target surface. A S111aller
                                             a constant temperature is observed; noise
                                             equivalent temperature difference refers to
                                             the standard deviation [(dTr..,l)a\·1°·5 of
                                             radiance temperature Th measured with
                                             the infrared thermographic system. This
                                             technique confums the objectiveness of
                                             data with no personal error when reading
                                             the scale.
                                             Theoretical Background
                                             Minimum Detectable Size
                                             Planck's radiation law is known to govern
                                             the spectral radioslty H\ of a blackbody. A
                                             simple expression of the relationship
                                             between blackbody temperature T~ and
                                             radiance L is the extended power of
                                             radiosity. In this rase, when the radiation
                                             from a bhKkbody having a core
                                             temperature T~ and a temperature change
                                             !!T, (< 7~) is n.wasured with th~ infrared
                                             thermographic sy~tem possessmg a
                                             detection wavelength band Q having a
                                             certain amplitude, then radiance L can be
                                             approximated by the following formul<l
                                             using Li.:H
                                                         Errors in Infrared Thermography 133
(1) L                                                                                                                                111~ 11         distance h + /Jo from the lens to the target
                                                                                                                                                                  surface being linked:
                                                                                                                                                                  (2) - +  1            1
           In the above, A is a constant and t 1• is the                                                                                                          a b + 1>0             r
           spectral radiance depending on                                                                                                                         ~he .following formula is applicable
           wavelength/.... The exponent u can be
           derived by integrating the product of                                                                                                                  !mkmg the square sensor area, An to the
           Plan~k'~ radiation _law and the detectivity
           pertammg to the mfrared thermographic                                                                                                                  ~ rmstantaneous measurement area AT:
           system with wavelength /,,6,7 A detected                                                                                                               (3) Ay   ( b : bo AD
           energy spectrum is obtained {Fig. I) and,                                                                                                               Note that the distance from the lens to
                                                                                                                                                                  the window is b0 •
           by using the least squares technique,
           11 is then derived from a nearly                                                                                                                          Because ll minimum detectable size M 0
                                                                                                                                                                  determined theoretically corresponds to
           straight line to become 4.31 for the                                                                                                                   the real image of the infrared sensor
           mercury cadmium telluride infrared                                                                                                                     projected on the target surface to be
           sensor, having a 8 to 13 pm detection
                                                                                                                                                                  measured, by inserting the practical values
           wavelength band. This value of 11 s!10uld                                                                                                              pertaining to the infrared thennographic
                                                                                                                                                                  system into Eqs. 2 and 3, Mo = (kr)o.s can
           vary as a function of n and of the
                                                                                                                                                                  be derived for every objective distance
           temperature range because of the
                                                                                                                                                                  B = b + b0 . When the size of a target to be
           transmission function. The temperature                                                                                                                 measured is larger than lv/0 , the radiance
           range considered is 300.2 to 373.2 K                                                                                                                   temperature 1~5 of the target surface itself
                                                                                                                                                                  can be determined. But if the size of the
           (27.0 to 100.0 "C; 80.6 to 212.0 "F).                                                                                                                  target is smaller than M0, even when
              Figure 2 is a schematic of the infrared                                                                                                             using an ideal device with a distortion
                                                                                                                                                                  free lens, the data include not only energy
           thermographic system as vie'ived from the
                                                                                                                                                                  emitted from the target surface but also
           aspect of a temperature gage (the
           scanning system is omitted here). The                                                                                                                  ;,nergy emitte.d from the surroundings.
                                                                                                                                                                  I he surroundmgs affect the signal and
           following formula links (a) the lens focal                                                                                                             hence the quantitative determination of
           length{, (b) the separation a between the
           infrared sensor and the lens and (c) the                                                                                                               temperature.
FIGURE 1. Energy detected with mercury-cadmium-tellurium                                                                                                          . Ordinarily, in a thermal image from an
sensor having 8 to 13 ~m wavelength band): In (y) ~                                                                                                               mfrared thermographic system, the
Ao +A, In (x) where A0 ~ 31.334 and A1 ~ 4.3069.
                                                                                                                                                                  thermal index Trs indicated with the
4                                                                                                                                                                 infrared thermographic system is
   "::-::  Ec=·'     -~t:~~                                                                                                 A1 ln {x)                             represented as an area averaged Tr~ within
                                                                                                                                                                  Mo composing the image. As indicated in
           -      In (y)
= = ='I
   --             Ao=-31.334                                                                                                                               -
E
.s t= •~
3  1- ~        -           A1 "'4.3069                                                                                                               -~
   1-                                        -                                                                                                    -
                  -I-I---- --
r= =CJ ,-
   !~ r--- 1:=                                                                                                                 -~        -;:,'·I              -
=~ 2 - - -                                                                                                                             c- ~,b              -~
                  I-                                                                                                           -                                  FIGURE 2. Optical model.
                          -~                                                                                                    -      ~                    --
                                                                                                                                                                         b--~-bo-t-- o-~
                                                                                                                                 --                           -
cID - ·- - - -- -                                                                                                                       ~
                                                                                                                            -
ID                                                                                                                             -~ ~'¢
                                                                                                                        ~-
,.".'{ju - - -
               --
                        --                                                                                                     " -~
                  -
* + l;v1- ·-I-I--- ~ -                                                                                                                                     -
0 1-                                                                                                                                                                                            1\~
473                                                                                                                             S73                         673                -    .. ~-1;[]
(200)                                                                                                                          (300)                       (400)
[392]                                                                                                                          [S72]                       [7S2]  Measurement area         J~"'
                 Blackbody temperature r.,, K (0 C) {°F)                                                                                                                                                                                 ~
legend                                                                                                                                                                                    \"'indow
 - ==instrumented measurements                                                                                                                                                                        Objec!ive
   Ao =area                                                                                                                                                                                              lens
    A1 ==area
   Ot, =- blackbody emis5ion                                                                                                                                      legend
     T = temperature
                                                                                                                                                                    An = sensor area
   r=x =variable
          variable                                                                                                                                                   A, =measurement area
     a= standard deviation                                                                                                                                            a=- distance from sensor to !en~
                                                                                                                                                                      b =distance from target surface to observation window
                                                                                                                                                                     bo =distance from lem to ob5ervation window
134 Infrared and Thermal Testing
Fig. 3, when measuring a target surface                                                                is defined as a temperature change such
having radiation energy Ez(Trsz),                                                                      that the ratio of signal S to noise N of the
representing Tn2, consider the case that                                                               infrared thermographic system becomes
the component (slit width) M having the                                                                1.0 around T~:
radiation energy E 1 (7~~ 1 ), representing Tr~l
and being higher than E2(Tr52), exists as                                                              (6) NETD
an adequately long vertical shape (slit)
within M0 . The averaged radiation energy                                                                 A simplified schematic of the infrared
E,;,(Tr~_,) received at the infrared sensor is                                                         thermographic system from which the
determined in proportion to the area                                                                   scanning unit is removed is shown in
ratio M·M0- 1:                                                                                         Fig. 4. \.Yhen the minute temperature
                                                                                                       change /1T5 occurs on the target surface,
                    ~MoE 1(Trsl )                                                                      the corresponding minute change LJ.E1•
                                                                                                       occurring in the energy E>. incident on the
                           +  M0M-        M  E (T )                                                    infrared sensor can be expressed as Eq. 7
                                               2 rs2                                                   with transmission coefficient r0 of air,
                                       0                                                               optical system transmission coefficient 1).,
                                                                                                       spectral emissivity£>._, measurement area
   Trsl, Trs2 and Trsx are the thermal                                                                 A'f; effective solid angle nT(dfJ and minute
indices of the infrared thermographic                                                                  change M>. in spectral radiance LJ,:
system as indicated below:
                                                                                                       (7)
(5) E,                     "cr1~s 1 '
                                                                                                          The physical quantities used in Eq. 7
Ez aTrs211 '                                                                                           are linking to each other in accordance
"Ex cr7~s.\                                                                                            =(:with the following relations when B >> f
where cr = Stefan-lloltzmann's constant                                                                and n
and 11 = sensor intrinsic constant
(mentioned above).
Noise Equivalent Temperature                                                                           (8) Ar       B2               Jl2
Difference
                                                                                                                    -a2A v           -[ 2A n
The noise equivalent temperature
difference (NETD) for a target surface                                                                               l~r
maintained at a constant temperature T~
                                                                                                                    n -B-z -
                                                                                                       (9) QT{eff)
fiGURE 3. Average energy.
                                                                                                       FIGURE 4. Optical schematic.
                 : 1-,-------                                                                          ' t I· .~8--
                                                                                              f1{T,1)                                           <o
                                                                         I                                                                         1
                                                         I f,(T,,)
                                                                                                                                              /\~~
Legend                                                                                                         \ r;l] Ao
     [ = radiation energy                                                                              ih(ffl) \I--------~
    E,. =averaged radiation energy                                                                     A, ,,
   M =slit width
                                                                                                       legend
  M0 == minimum detectable 5ize
                                                                                                             A0 =sensor area
                                                                                                             A1 = mea5urement area
                                                                                                              o"' distance from 5ensor to !ens (millimeter)
                                                                                                               B =objective distance from targel5urface to !em
                                                                                                               E = emhsivity
                                                                                                              4> =lens diameter (millimeter)
                                                                                                              '~=special propagation coefficient
                                                                                                              t)_ =propagation coefficient of optical system
                                                                                                         H1 <•-II) =effective solid angle
                                                                                                                    Errors in Infrared Thermography 135