Covalen
• The type of electrical
atoms are held togeth
attraction for shared e
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
nt Bonds
attraction in which
her by their mutual
electrons.
on-Wesley
Covalen
• The type of electrical
atoms are held togeth
attraction for shared e
• There are two electro
covalent bond.
• The covalent bond is
straight line.
FF
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
nt Bonds
attraction in which
her by their mutual
electrons.
ons within a single
represented using a
F—F
on-Wesley
Covalen
• The number of covale
form equals its numbe
electrons.
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
nt Bonds
ent bonds an atom can
er of unpaired valence
on-Wesley
Covalen
• The number of covale
form equals its numbe
electrons.
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
nt Bonds
ent bonds an atom can
er of unpaired valence
on-Wesley
Covalen
• The number of covale
form equals its numbe
electrons.
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
nt Bonds
ent bonds an atom can
er of unpaired valence
on-Wesley
Covalen
• The number of covale
form equals its numbe
electrons.
• Multiple covalent bond
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
nt Bonds
ent bonds an atom can
er of unpaired valence
ds are possible.
on-Wesley
Non-polar Co
• Electrons within a cov
evenly when the two a
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
ovalent Bonds
valent bond are shared
atoms are the same.
on-Wesley
Polar Cova
• Electrons within a cov
evenly when the two a
• They may be shared u
when the bonded atom
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
alent Bonds
valent bond are shared
atoms are the same.
unevenly, however,
ms are different.
on-Wesley
Polar Cova
• Electrons within a cov
evenly when the two a
• They may be shared u
when the bonded atom
• Electronegativity: The
atom to pull on shared
electronegativity mean
power.”
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
alent Bonds
valent bond are shared
atoms are the same.
unevenly, however,
ms are different.
e ability of a bonded
d electrons. Greater
ans greater “pulling
on-Wesley
Polar Cova
• Electronegativity: The
atom to pull on shared
electronegativity mean
power.”
Low
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
alent Bonds
e ability of a bonded
d electrons. Greater
ans greater “pulling
High
on-Wesley
Polar Cova
• Electronegativity: The
atom to pull on shared
electronegativity mean
power”.
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
alent Bonds
e ability of a bonded
d electrons. Greater
ans greater “pulling
on-Wesley
Polar Cova
CHECK YOU
Which is heavier: carbon dioxi
A. Carbon dioxide is heavier.
B. Water is heavier.
C. They both have the same num
same.
D. It depends.
Explanation:
Look to the Periodic Table and ad
each of these substances. Carbon
water is only 18 amu. So, carbon d
At room temperature, carbon dioxi
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
alent Bonds
UR ANSWER
ide, CO2, or water, H2O?
mber of atoms so they weigh the
dd up the masses of the atoms within
n dioxide adds up to 44 amu, while
dioxide is more than twice as heavy.
ide is a gas because it is nonpolar.
on-Wesley
Molecula
• But if polar bonds with
facing in equal and op
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
ar Polarity
hin a molecule are
pposite directions…
on-Wesley
Molecula
• But if polar bonds with
facing in equal and op
…then the polarity ma
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
ar Polarity
hin a molecule are
pposite directions…
ay cancel itself out.
on-Wesley
Molecula
• But if polar bonds with
facing in equal and op
…then the polarity ma
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
ar Polarity
hin a molecule are
pposite directions…
ay cancel itself out.
…or not!
on-Wesley
Molecula
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
ar Polarity
on-Wesley
Molecular
CHECK YOUR
Water has such a relatively hig
water
A. is such a heavy substance.
B. is transparent so that heat pass
C. contains three atoms per molec
D. molecules are so sticky.
Explanation:
The slightly negative end of one
slightly positive end of another
attraction must be overcome be
transform into the gaseous pha
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
r Polarity
R NEIGHBOR
gh boiling point because
ses right through it.
cule.
e water molecule holds onto the
water molecule. This force of
efore the liquid water can
ase.
on-Wesley
Molecular A
• Ion–dipole
The attraction betwe
dipole. Example: Na
H OH H
Na+ O
H
HO
H
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
Attractions
een an ion and a
aCl in water.
OH HO
H Cl- H
H H
O
on-Wesley
Molecular A
• Ion–dipole
The attraction betwe
dipole. Example: Na
• Dipole–dipole
The attraction betwe
two dipoles.
Example: cohesive
forces within water.
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
Attractions
een an ion and a
aCl in water.
een
on-Wesley
Molecular A
• Ion–dipole
The attraction betwe
dipole. Example: Na
• Dipole–dipole
The attraction betwe
Example: cohesive f
• Dipole–induced dipole
The attraction betwe
induced dipole.
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
Attractions
een an ion and a
aCl in water.
een two dipoles.
forces within water.
e
een a dipole and an
on-Wesley
Molecular A
• Dipole–induced dipole
The attraction betwe
induced dipole.
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
Attractions
e
een a dipole and an
on-Wesley
Molecular A
CHECK YOU
A nonpolar material, such as o
polar material, such as water,
A. ion–dipole attractions.
B. dipole–dipole attractions.
C. dipole–induced dipole attrac
D. All of the above.
Explanation:
This is a relatively weak force o
not much oxygen dissolves in th
however, to allow fish to live.
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
Attractions
UR ANSWER
oxygen, O2, is soluble in a
H2O, by way of
ctions.
of attraction, which explains why
he water. There is enough,
on-Wesley
Molecular A
A fourth molecula
induced dipole-ind
occurs between no
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
Attractions
ar attraction is the
duced dipole, which
onpolar molecules.
on-Wesley
Molecular A
Nonpolar atoms are attracted to each
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
Attractions
other by these “momentary” dipoles,
on-Wesley
Molecular A
The larger the atom, the stro
Copyright © 2008 Pearson Education, Inc., publishing as Pearson Addiso
Attractions
onger the “momentary” dipole.
on-Wesley