PROCESS
SAFETY
LESSONS
TAUGHT FROM EXPERIENCE
“Community should have the right to know
about the nature of the chemicals being
handled in the nearby chemical
manufacturing units, their preparedness for
and their response to any chemical
emergency.”
Source: http://www.erris.org
2
MAJOR
INDUSTRIAL
DISASTERS
INCIDENTS THAT DEFINE PROCESS SAFETY
Explosion
Toxic
Release
Runaway
Reaction
Prepared by: 3
Dr Wan Rafizah Wan Abdullah
2016
THEBHOPAL GAS
UNFINISHEDTRAGEDY, 1984
STORY
4
FACTS
Location: Bhopal, India Date: December 2, 1984
Cause: (Runaway reaction & Toxic Release) 5
• Exothermic reaction between contaminated methyl
isocyanate (MIC) and water causing runaway reaction.
• 25 tons of MIC vapor released.
Aftermath: Toxic cloud spread nearby town poisoning/killing
2500 and up to 10 000 in the first 3 days, injured more than
20,000.
Lesson Learned:
• Expanding industrialization in developing countries without
concurrent evolution in safety regulations could have
catastrophic consequences.
• Enforceable uniform international operating regulations for
hazardous industries would have provided a mechanism
for significantly improved in safety.
• International standards could provide norms for measuring
performance of individual companies engaged in
hazardous activities.
DIOXIN CRISIS,
SEVESO, ITALY,
1976
CATASTROPHE DE SEVESO
2000 dioxin poisoning 200 inured
730 evacuated 10 miles2 immediate contamination
6
FACTS
Location: Seveso, Italy Date: July 10, 1976
Cause: (Runaway reaction & Toxic
Release)
• Reactor out of control, produced
excessive side product of
extremely toxic TCDD (Dioxin)
• 2 kg of vapor TCDD released to
atmosphere through relief system
and heavy rain washed into soil.
Aftermath: 2000 were treated for dioxin poisoning, 200
inured, 730 people evacuated, immediate contamination of 10
miles2 of land and vegetation
Lesson Learned: 7
• The complexity of communication problems under
conditions of severe uncertainty was recognized,
• Before the incident, no one outside the plant neither
residents nor political or health authorities - had any idea
that there was a hazard of such magnitude.
• The authorities had their own severe problems of decision-
making under uncertainty, including the definition of
different polluted zones, programmes of evacuation of
endangered residents, and disposal of contaminated
material.
• Legislation aimed at the prevention and control of
accidents involving dangerous substances in the EU was
significantly prompted (Seveso Directive)
FLIXBOROUGH
EXPLOSION,
1974
History of unsafe processes
Explosion equivalent to 15 ton of TNT!
8
FACTS
Location: Flixborough, UK Date: June 1, 1974
Cause: (Explosion)
• Release of 85 000 lbs of
flammable mixture (ethylene,
isobutyl, hexane, hydrogen) when
a bypass system ruptured.
• Gas cloud was ignited by
unidentified source, causing
massive explosion.
Aftermath: 28 workers were killed, 36 were severely
injured, 1800 buildings were damaged, the loss is equivalent
with approx. $200 millions at present value.
Lesson Learned:
• There was no professional engineer in the plant at the time
of the accident. The temporary modification was
constructed by people who did not know to design large
pipes equipped with bellows.
• The most important lesson that Flixborough taught is the
need to minimize inventories of hazardous materials.
• The disaster led to a widespread public outcry over
industrial plant safety, and significant tightening of the UK
government's regulations covering hazardous industrial
processes.
9
nuclearEPIC crisisFUKUSHIMA
DAIICHI NUCLEAR
DISASTER, 2011
10
FACTS
Location: Fukushima Daiichi, Japan
Date: March 11, 2011
Cause: Aftermath: The accident prompted
widespread evacuations of local
(Toxic release, explosion, populations, large economic losses,
natural disaster) and the eventual shutdown of all
nuclear power plants in Japan.
• Great East Japan Massive radioactive contamination of
Earthquake and the Japanese mainland. Estimated
tsunami initiated a total economic loss range from $250-
severe nuclear 500 billion US.
accident at the
Fukushima Daiichi Lesson Learned:
Nuclear Power
Station. ?
11
• Three of the six
reactors at the plant
sustained severe core
damage and released
hydrogen and
radioactive materials.