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สารประกอบเชิงซ้อน

งานนำเสนอ3

Coordination Compound

สารประกอบเชงิ ซอ้ น

จดั ทาโดยนางสาว วรรณกิ า ขนาบศกั ดิ์
รหัสนกั ศกึ ษา 5981108005

สารบญั 1
2
K[Pt(NH3)Cl5] 3
[Cu(CN)4]3- 4
[Co(en)2Br2]2SO4 5
Ba[FeBr4]2 6
[Cr(NH3)5(NO2)]2+ 7
[Zn(en)F2] 8
[Ni(H2O)6]Cl2 9
[Pt(en)2]CO3
[Pt(NH3)6]Cl4 10
[Cu(NH3)4(H2O)2]Cl2

K[Pt(NH3)Cl5]

Complex ion : [Pt(NH3)Cl5]-
Counter ion : K+
Center ion : Pt4+
Oxidation number : +4
Ligand : NH3, 5Cl-
Coordination number : 6
Name : potassium amminepentachloro

platinate(IV)
78Pt4+ : 2 8 18 32 14

1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10
4f14 5s2 5p6 5d6

78Pt4+ : Paramagnetic

1

[Cu(CN)4]3-

Complex ion : [Cu(CN)4]3-
Counter ion : -
Center ion : Cu+
Oxidation number : +1
Ligand : 4CN-
Coordination number : 4
Name : tetracyanocuprate(I) ion
29Cu+ : 2 8 18

1s2 2s2 2p6 3s2 3p6 3d10

29Cu+ : Diamagnetic

2

[Co(en)2Br2]2SO4

Complex ion : [Co(en)2Br2]2+
Counter ion : SO42-
Center ion : Co3+
Oxidation number : +3
Ligands : 2en, 2Br-
Coordination number : 6
Name :
dibromobisethylenediaminecobalt(III)sulfate
27Co3+ : 2 8 14

1s2 2s2 2p6 3s2 3p6 3d6

27Co3+ : Paramagnetic

3

Ba[FeBr4]2

Complex ion : [FeBr4]2-
Counter ion : Ba2+
Center ion : Fe3+
Oxidation number : +3
Ligand : 4Br-
Coordination number : 4
Name : barium tetrabromoferrate(III)
26Fe3+ : 2 8 13

1s2 2s2 2p6 3s2 3p6 3d5

26Fe3+ : Paramagnetic

4

[Cr(NH3)5(NO2)]2+

Complex ion : [Cr(NH3)5(NO2)]2+
Counter ion : -
Center ion : Cr3+
Oxidation number :+3
Ligands : 5NH3, NO2-
Coordination number : 6
Name : pentaamminenitritochromium(III) ion
24Cr3+ : 2 8 11

1s2 2s2 2p6 3s2 3p6 3d3

24Cr3+ : Paramagnetic

5

[Zn(en)F2]

Complex ion : [Zn(en)F2]
Counter ion : -
Center ion : Zn2+
Oxidation number : +2
Ligands : en, 2F-
Coordination number : 4
Name : ethylenediaminedifluorozinc(II)
30Zn2+ : 2 8 18

1s2 2s2 2p6 3s2 3p6 3d10

30Zn2+ : Diamagnetic

6

[Ni(H2O)6]Cl2

Complex ion : [Ni(H2O)6]+
Counter ion : 2Cl-
Center ion : Ni2+
Oxidation number : +2
Ligand : 6H2O
Coordination number : 6
Name : hexaaquanickel(II) chloride
28Ni2+ : 2 8 16

1s2 2s2 2p6 3s2 3p6 3d8

28Ni2+ : Paramagnetic

7

[Pt(en)2]CO3

Complex ion : [Pt(en)2]2+
Counter ion : CO32-
Center ion : Pt2+
Oxidation number : +2
Ligand : 2en
Coordination number : 4
Name : bisethylenediamineplatinum(II)

carbonate
78Pt2+ : 2 8 18 32 16

1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14
5s2 5p6 5d8

78Pt2+ : Paramagnetic

8

[Pt(NH3)6]Cl4

Complex ion : [Pt(NH3)6]4+
Counter ion : 4Cl-
Center ion : Pt4+
Oxidation number : +4
Ligand : 6NH3
Coordination number : 6
Name : hexaammineplatinum(IV) chloride
78Pt4+ : 2 8 18 32 14

1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10
4f14 5s2 5p6 5d6

78Pt4+ : Paramagnetic

9

[Cu(NH3)4(H2O)2]Cl2

Complex ion : [Cu(NH3)4(H2O)2]2+
Counter ion : 2Cl-
Center ion : Cu2+
Oxidation number : +2
Ligands : 4NH3, 2H2O
Coordination number : 6
Name : tetraamminediaquacopper(II)
chloride
29Cu2+ : 2 8 17

1s2 2s2 2p6 3s2 3p6 3d9

29Cu2+ : Paramagnetic

10


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