MIND MAP CHAPTER 10 CARBOXYLIC ACID

MIND MAP
CARBONYL
COMPOUNDS

Prepared by: NFAG, KMPh

PREPARATION AND CHEMICAL PROPERTIES OF CARBONYL

(ALDEHYDE) [O] reagent & condition:
KMnO4 @ K2Cr2O7 @ Na2Cr2O7, H+/

CH3MgCl CH3CN O PCC OH
CH3CH CH2Cl2 CH3CH

i) CO2 H2O, H+ K2Cr2O7 / H+ KMnO4 / H+ H
ii) H3O+
O [O] Alkybenzene form
benzoic acid

- Na+ Na @ NaOH @ O CH3OH, H + O
CH3CO Na2CO3 @ NaHCO3 CH3COH CH3CO-CH3
reflux
OO
O Mg CH3COOH
P2O5 , heat CH3COCCH3
- 2Mg 2 + i. LiAlH4, ether NH3 Heat
CH3CO
ii. H3O+
SOCl2, pyridine

@ PCl3 @ PCl5

H

CH3C-OH O O Anhydride formation:
H CH3CCl CH3CNH2
Reagent & condition
Amide formation: CH3COCl , pyridine
@ CH3COOH / P2O5, heat

Reagent & condition
NH3 @ RNH2 @ RNHR

Prepared by: NFAG, KMPh

Prepared by: NFAG, KMPh